Crystalline phases and YAG laser-induced crystallization in SM2O3-Bi2O3-B2O3 glasses

被引：21
作者：
Honma, T
Benino, Y
Fujiwara, T
Komatsu, T [1 ]
Sato, R
机构：
[1] Nagaoka Univ Technol, Dept Chem, Nagaoka, Niigata 9402188, Japan
[2] Tsuruoka Natl Coll Technol, Dept Mat Engn, Tsuruoka 9978511, Japan
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2005年 / 88卷 / 04期
关键词：
D O I：
10.1111/j.1551-2916.2005.00166.x
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The glass formation region, crystalline phases, second harmonic (SH) generation, and Nd:yttrium aluminum garnet (YAG) laser-induced crystallization in the Sm2O3-Bi2O3-B2O3 system were clarified. The crystalline phases of Bi4B2O9, Bi3B5O12, BiBO3, SmxBi1-xBO3, and SmB3O6 were formed through the usual crystallization in an electric furnace. The crystallized glasses consisting of BiBO3 and SmxBi1-xBO3 showed SH generations. The formation of the nonlinear optical BiB3O6 phase was not confirmed. The formation (writing) region of crystal fines consisting of SmxBi1-xBO3 by YAG laser irradiation was determined, in which Sm2O3 contents were similar to 10 mol%. The present study demonstrates that Sm2O3-M2O3-B2O3 glasses are promising materials for optical functional applications.
引用
收藏
页码：989 / 992
页数：4
相关论文
共 21 条
[1]  
[Anonymous], 1961, J CERAM ASS JPN, DOI DOI 10.2109/JCERSJ1950.69.789_282
[2]   Thermal and optical properties of glasses of the system Bi2O3-B2O3 [J].
Becker, P .
CRYSTAL RESEARCH AND TECHNOLOGY, 2003, 38 (01) :74-82
[3]   STRUCTURE-PROPERTY RELATIONS IN LANTHANIDE BORATE GLASSES [J].
CHAKRABORTY, IN ;
DAY, DE ;
LAPP, JC ;
SHELBY, JE .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1985, 68 (07) :368-371
[4]  
DUMBAUGH WH, 1986, PHYS CHEM GLASSES, V27, P119
[5]  
Hellwig H, 1999, SOLID STATE COMMUN, V109, P249, DOI 10.1016/S0038-1098(98)00538-9
[6]   Technique for writing of nonlinear optical single-crystal lines in glass [J].
Honma, T ;
Benino, Y ;
Fujiwara, T ;
Komatsu, T ;
Sato, R .
APPLIED PHYSICS LETTERS, 2003, 83 (14) :2796-2798
[7]   Nonlinear optical crystal-line writing in glass by yttrium aluminum garnet laser irradiation [J].
Honma, T ;
Benino, Y ;
Fujiwara, T ;
Komatsu, T ;
Sato, R .
APPLIED PHYSICS LETTERS, 2003, 82 (06) :892-894
[8]   New optical nonlinear crystallized glasses and YAG laser-induced crystalline dot formation in rare-earth bismuth borate system [J].
Honma, T ;
Benino, Y ;
Fujiwara, T ;
Sato, R ;
Komatsu, T .
OPTICAL MATERIALS, 2002, 20 (01) :27-33
[9]   Optical nonlinear crystalline dot and line patterning in samarium bismuth borate glasses by YAG laser irradiation [J].
Honma, T ;
Benino, Y ;
Fujiwara, T ;
Sato, R ;
Komatsu, T .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2002, 110 (05) :398-402
[10]  
Honma T, 2002, PHYS CHEM GLASSES, V43, P32
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