Metal Polysulfides of Groups 4-6: From Bulk Samples to Nanoscale Materials

被引：7

作者：

Artemkina, S. B. ^{[1
]}

Kozlova, M. N. ^{[1
]}

Poltarak, P. A. ^{[1
,2
]}

Grayfer, E. D. ^{[1
]}

Fedorov, V. E. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 04期

基金：

俄罗斯科学基金会;

关键词：

polysulfides; transition metals; low-dimensional structures; colloidal dispersions; nanomaterials; cathode materials; photocatalysis; LIQUID-PHASE EXFOLIATION; NIOBIUM TRISULFIDE; COLLOIDAL DISPERSIONS; ELECTRODE MATERIALS; TUNGSTEN SULFIDES; HYDROGEN PHOTOGENERATION; VANADIUM TETRASULFIDE; ZIRCONIUM TRISULFIDE; CRYSTAL-STRUCTURES; NANOSHEETS;

D O I：

10.1134/S0022476618040248

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The article discusses the current state of research concerning transition metal polysulfides of groups 4-6. We review the data on the preparation of nanoscale polychalcogenides from elements or molecular precursors and by exfoliating bulk samples. Particular attention is paid to the ultrasound liquid-phase exfoliation of typical polysulfides such as NbS3, TaS3, VS4. The main feature of this class of compounds is the presence of disulfide groups (S-S)(2-) which determine most important structural, physical, and chemical properties of these compounds to make them effective catalysts and electrodes in electrochemical cells.

引用

页码：913 / 921

页数：9

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