Superwetting meshes with grass-like structures in the pores for highly efficient separation of oil-in-water emulsion

被引:17
作者
Wen, Qiuying [1 ,2 ,3 ]
Guo, Fei [1 ,2 ,3 ]
Peng, Yubing [1 ,2 ,3 ]
Guo, Zhiguang [1 ,2 ,3 ]
机构
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Hubei, Peoples R China
[2] Hubei Univ, Key Lab Green Preparat & Applicat Funct Mat, Minist Educ, Wuhan 430062, Hubei, Peoples R China
[3] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China
关键词
Grass-like; Superhydrophilic in air; Superoleophobic under water; Oil-in-water emulsion separation; OIL/WATER SEPARATION; ROBUST; MEMBRANE; FABRICATION; PARTICLES; SUPERHYDROPHOBICITY; MICROFILTRATION; ADSORPTION; RESISTANCE; MIXTURES;
D O I
10.1016/j.colsurfa.2017.07.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Superwetting membranes offer an important route for oil/water separation, yet there still exist some challenges such as simple preparation process, cyclic utilization. Here, superwetting stainless steel meshes (SSMs) covered by micro/nano structured Cu and Cu(OH)(2) were successfully prepared via a simple electrodeposition followed by a fast oxidation process. The obtained meshes exhibited superhydrophilic in air and superoleophobic under water property, which can effectively separate surfactant-stabilized oil-in-water emulsion only under gravity or a low applied pressure (0.1 bar) and can circularly separate emulsion. In addition, the pore size and structure can be controlled through changing the electrodeposition time and the effects of the electrodeposition time on the permeation flux were studied in this paper. The prepared meshes may possess potential application for the practical oil/water separation.
引用
收藏
页码:1030 / 1036
页数:7
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