Enantioselective nucleophilic substitution of a 6,6-bicyclic dienyl acetate by palladium-chiral phosphine catalyst

被引：14

作者：

Shimizu, I ^{[1
]}

Matsumoto, Y ^{[1
]}

Nishikawa, M ^{[1
]}

Kawahara, T ^{[1
]}

Satake, A ^{[1
]}

Yamamoto, A ^{[1
]}

机构：

[1] Waseda Univ, Sch Sci & Engn, Dept Appl Chem, Shinjuku Ku, Tokyo 1698555, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 10期

关键词：

D O I：

10.1246/cl.1998.983

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantioselective nucleophilic substitution of (+/-)-2 beta-acetoxy-4a beta-methyl-2,3,4,4a, 5,6-hexahydronaphthalene with dimethyl malonate anion was performed in the presence of palladium-chiral ligand catalysts to give optically active 2-di(methoxycarbonyl)methyl-4a-methyl-2,3,4,4a,5, 6-hexahydronaphthalenes.

引用

页码：983 / 984

页数：2

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