Measurement and temperature dependence of the water vapor self-continuum between 70 and 700 cm-1

被引:23
作者
Odintsova, Tatyana A. [1 ]
Tretyakov, Mikhail Yu [1 ]
Simonova, Anna A. [2 ]
Ptashnik, Igor, V [2 ]
Pirali, Olivier [3 ,4 ]
Campargue, Alain [5 ]
机构
[1] RAS, Inst Appl Phys, Nizhnii Novgorod, Russia
[2] VE Zuev Inst Atmospher Opt SB RAS, Tomsk, Russia
[3] SOLEIL Synchrotron, LOrme Merisiers, F-91192 Gif Sur Yvette, France
[4] Univ Paris Saclay, Inst Sci Mols Orsay, CNRS, F-91405 Orsay, France
[5] Univ Grenoble Alpes, LIPhy, CNRS, F-38000 Grenoble, France
关键词
FT-Spectroscopy; Water vapor; Rotational band; Bimolecular absorption; Continuum; Temperature dependence; ATMOSPHERIC WINDOW; SPECTRAL REGION; MU-M; ABSORPTION; H2O; PARAMETERS; MIXTURES; DIMER; MODEL; GHZ;
D O I
10.1016/j.molstruc.2020.128046
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present new measurements and analysis of the water absorption spectra in the region of the rotational band, between 70 and 700 cm(-1). The higher pressures of the recordings (up to 16 mbar) as compared to our previous measurements allowed us to extend the retrieval of the water vapor self-continuum absorption from 500 to 700 cm(-1) and to test our earlier results up to 500 cm(-1). As a result, the continuum amplitude at high wavenumbers, determined with smaller uncertainty, shows an improved agreement with literature experimental data. The measurements were performed at two temperatures (296 and 326 K) using two radiation sources of significantly different power ranges: SOLEIL synchrotron and globar. The quadratic pressure dependence of the self-continuum absorption was verified leading to consistent values of cross-sections derived at various experimental conditions. In addition, we obtained the first data concerning the water vapor self-continuum temperature dependence in the 84-365 cm(-1) spectral range for which we present the preliminary analysis considering the available measurements and theoretical data. (C) 2020 Elsevier B.V. All rights reserved.
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页数:7
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