Electron-Induced Hydration of an Alkene: Alternative Reaction Pathways

被引：18

作者：

Warneke, Jonas ^{[1
]}

Wang, Ziyan ^{[1
]}

Swiderek, Petra ^{[1
]}

Bredehoeft, Jan Hendrik ^{[1
]}

机构：

[1] Univ Bremen, Inst Angew & Phys Chem, D-28359 Bremen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 14期

关键词：

alkenes; electron-induced reactions; radical ions; reaction mechanisms; water; LOW-ENERGY ELECTRONS; INDUCED HYDROAMINATION; DISSOCIATION; MOLECULES; HYDROCARBONS; ATTACHMENT; ETHYLENE; FILMS; DNA;

D O I：

10.1002/anie.201412147

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron-induced reactions in condensed mixtures of ethylene and water lead to the synthesis of ethanol, as shown by post-irradiation thermal desorption spectrometry (TDS). Interestingly, this synthesis is not only induced by soft electron impact ionization similar to a previously observed electron-induced hydroamination but also, at low electron energy, by electron attachment to ethylene and a subsequent acid/base reaction with water.

引用

页码：4397 / 4400

页数：4

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