Metal-Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible Light

被引：659

作者：

Neumann, Matthias ^{[1
]}

Fueldner, Stefan ^{[1
]}

Koenig, Burkhard ^{[1
]}

Zeitler, Kirsten ^{[1
]}

机构：

[1] Univ Regensburg, Inst Organ Chem, D-93053 Regensburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 04期

关键词：

asymmetric alkylation; cooperative catalysis; organocatalysis; photocatalysis; xanthene dyes; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; PHOTOINDUCED ELECTRON-TRANSFER; SENSITIZED SOLAR-CELLS; PHOTOREDOX CATALYSIS; PHENACYL HALIDES; DOMINO REACTIONS; XANTHENE DYES; ORGANIC-DYES; ALDEHYDES; ALKYLATION;

D O I：

10.1002/anie.201002992

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dawn of old stars: Classic xanthene dyes like eosin Y (gr. I=goddess of dawn) and green-light irradiation can replace precious metal complexes for the organocatalytic asymmetric α-alkylation of aldehydes, thus rendering the process purely organic. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：951 / 954

页数：4

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