Removal of borate by coprecipitation with Mg/Al layered double hydroxide

被引:8
作者
Kurashina, Masashi [1 ]
Inoue, Tatsuki [1 ]
Tajima, Chihiro [1 ]
Kanezaki, Eiji [1 ]
机构
[1] Univ Tokushima, Fac Engn, Dept Chem Sci & Technol, Tokushima 7708506, Japan
来源
MODERN PHYSICS LETTERS B | 2015年 / 29卷 / 6-7期
关键词
Layered double hydroxide; removal of borate; coprecipitation; HYDROTALCITE-LIKE COMPOUNDS; BORON REMOVAL;
D O I
10.1142/S021798491540031X
中图分类号
O59 [应用物理学];
学科分类号
摘要
Borate has been used for various industrial products and excessive dose of boron is harmful to humans. We investigated the removal of borate by direct coprecipitation with Mg/Al layered double hydroxide. In this study, the maximum removal of boron was 90% when Mg 30 mmol and Al 15 mmol at pH = 10 were used for 498 mg/l as B. The boron adsorption isotherms could be fitted to Langmuir model. The calculated constant W-s, saturation limit of boron adsorption, is 25 +/- 2 mg/g and it is larger than that of ion exchange reaction (W-s = 15 +/- 1 mg/g).
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页数:5
相关论文
共 12 条
  • [1] Allman, 1969, J MINERAL GEOCHEM, P544
  • [2] [Anonymous], 2018, Guidelines for Drinking Water Quality
  • [3] [Anonymous], 2011, CLAY SCI
  • [4] Boron removal by hydrotalcite-like, carbonate-free Mg-Al-NO73-LDH and a rationale on the mechanism
    Ay, Ahmet Nedim
    Zuemreoglu-Karan, Birguel
    Temel, Abidin
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 98 (1-3) : 1 - 5
  • [5] Layered double hydroxides with interlayer borate anions: A critical evaluation of synthesis methodology and pH-independent orientations in nano-galleries
    Ay, Ahmet Nedim
    Zumreoglu-Karan, Birgul
    Temel, Abidin
    Mafra, Luis
    [J]. APPLIED CLAY SCIENCE, 2011, 51 (03) : 308 - 316
  • [6] Calcined Mg-Fe-CO3 LDH as an adsorbent for the removal of selenite
    Das, J.
    Patra, B. Sairam
    Baliarsingh, N.
    Parida, K. M.
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 316 (02) : 216 - 223
  • [7] Adsorption of phosphate by layered double hydroxides in aqueous solutions
    Das, J.
    Patra, B. S.
    Baliarsingh, N.
    Parida, K. M.
    [J]. APPLIED CLAY SCIENCE, 2006, 32 (3-4) : 252 - 260
  • [8] Ferreira OP, 2006, CHEMOSPHERE, V62, P80, DOI 10.1016/j.chemosphere.2005.04.009
  • [9] ANION-EXCHANGE PROPERTIES OF HYDROTALCITE-LIKE COMPOUNDS
    MIYATA, S
    [J]. CLAYS AND CLAY MINERALS, 1983, 31 (04) : 305 - 311
  • [10] OZAWA T, 1986, BUNSEKI KAGAKU, V35, P709