Emission intensity enhancement of DC arc plasma induced by external oscillating magnetic field

Direct current (dc) arc plasma with continuous aerosol supply was coupled with an external oscillating magnetic field of a few tens of mT and a frequency of up to 1 kHz. Such configuration was used to alter the plasma-related radiative properties. The magnetic field was oriented perpendicularly to the electric field in the plasma and forced the arc column to oscillate as a whole with respect to the surrounding atmosphere. The magnitude of the applied magnetic field controls the amplitude of the oscillatory motion. Several parameters that can contribute to the radiative properties of the plasma were investigated (are current, composition of aerosol introduced into the plasma, amplitude and frequency of the magnetic field applied). Spectral emission from different zones of the plasma column was measured by optical emission spectroscopy (OES). In comparison to steady-state plasma, the applied magnetic field induces an intensity enhancement of emission of the most analytes considered. The intensity enhancement is strongly affected by the amplitude and frequency of plasma column oscillations, i.e. by plasma column velocity. Also, intensity enhancement depends on the plasma zone observed. (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.