Analytical-function correction to the Hartmann-Tran profile for more reliable representation of the Dicke-narrowed molecular spectra

被引:21
作者
Konefal, M. [1 ,2 ]
Slowinski, M. [1 ]
Zaborowski, M. [1 ]
Ciurylo, R. [1 ]
Lisak, D. [1 ]
Wcislo, P. [1 ]
机构
[1] Nicolaus Copernicus Univ Torun, Fac Phys Astron & Informat, Inst Phys, Ul Grudziadzka 5, PL-87100 Torun, Poland
[2] Univ Grenoble Alpes, CNRS, LIPhy, F-38000 Grenoble, France
关键词
Velocity-changing collisions; Hartmann-Tran profile; HTP; Speed-dependent billiard-ball profile; beta correction; Atmospheric molecular systems; LINE-SHAPES; CHANGING COLLISIONS; SPEED; LINESHAPE; PRESSURE; DOPPLER; SHIFT;
D O I
10.1016/j.jqsrt.2019.106784
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The beta-corrected Hartmann-Tran profile (HTP) constitutes an approximation of the partially correlated quadratic speed-dependent billiard-ball profile (SDBBP) easily applicable in calculations. We extend the approach originally developed for self-perturbed molecules [Wcislo et al. J. Quant. Spectrosc. Radiat. Transf. 177, 75-91 (2016)] to systems with a wide range of perturber-to-absorber mass ratios, including those relevant for atmospheric studies. This approach combines the computational simplicity of the HTP with the more physically justified rigid-sphere model for velocity-changing collisions. It is important for the analysis of high-resolution spectra influenced by the Dicke-narrowing effect. The beta-corrected HTP enables high quality analytical representation of experimental spectra without incurring the high computational cost of more advanced line-shape models. This correction is directly applicable to any other line-shape model based on the hard-collision model for velocity-changing collisions. (C) 2019 The Authors. Published by Elsevier Ltd.
引用
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页数:5
相关论文
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