The investigation of the bio-oil produced by hydrothermal liquefaction of Spirulina platensis using ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry

被引：17

作者：

Kostyukevich, Yury ^{[1
,2
,3
,4
]}

Vlaskin, Mikhail ^{[5
]}

Vladimirov, Gleb ^{[1
,2
]}

Zherebker, Alexander ^{[1
,2
,6
]}

Kononikhin, Alexey ^{[2
,4
]}

Popov, Igor ^{[3
,4
]}

Nikolaev, Eugene ^{[1
,2
,3
,4
]}

机构：

[1] Skolkovo Inst Sci & Technol, Skolkovo, Russia

[2] Russian Acad Sci, Inst Energy Problems Chem Phys, Moscow, Russia

[3] Russian Acad Sci, Emanuel Inst Biochem Phys, Moscow, Russia

[4] Moscow Inst Phys & Technol, Moscow, Russia

[5] Russian Acad Sci, JIHT, Moscow, Russia

[6] Lomonosov Moscow State Univ, Dept Chem, Moscow, Russia

来源：

EUROPEAN JOURNAL OF MASS SPECTROMETRY | 2017年 / 23卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

Bio-oil; isotopic exchange; dissolved organic matter; Fourier transform ion cyclotron resonance; ESI; SOURCE HYDROGEN/DEUTERIUM EXCHANGE; DISSOLVED ORGANIC-MATTER; SOURCE H/D EXCHANGE; ELECTROSPRAY-IONIZATION; ATMOSPHERIC-PRESSURE; O-16/O-18; EXCHANGE; TEMPERATURE; MICROALGAE; PYROLYSIS; SPECTRA;

D O I：

10.1177/1469066717702648

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

We report the investigation of the hydrothermal liquefaction products of the Spirulina platensis microalgae by using the Fourier transform ion cyclotron resonance mass spectrometry. The hydrothermal liquefaction produced two fractions: one with boiling temperature below 300(0)C and the dense residue that remained in the reactor. It was observed that N-2 and N classes of compounds that dominate in the positive ESI Fourier transform ion cyclotron resonance spectra for both fractions, and that the light fraction is considerably more saturated then the heavy one. The performed hydrogen/deuterium exchange reaction indicated the presence of the onium compounds in the bio-oil.

引用

页码：83 / 88

页数：6

共 31 条

[1] Optimization and Application of APCI Hydrogen-Deuterium Exchange Mass Spectrometry (HDX MS) for the Speciation of Nitrogen Compounds [J].