Template-free synthesis of hollow α-Fe2O3 microspheres

被引:10
作者
Song, Hao-Jie [1 ]
Li, Na [1 ]
Shen, Xiang-Qian [1 ]
机构
[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China
来源
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2011年 / 102卷 / 03期
基金
中国博士后科学基金;
关键词
MAGNETIC-PROPERTIES; FACILE ROUTE; NANORODS; SPHERES; FEOOH;
D O I
10.1007/s00339-010-6072-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nearly monodisperse hollow alpha-Fe2O3 microspheres composed of nanoparticles have been successfully synthesized through a facile template-free hydrothermal method. The products were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. It is shown that the hollow alpha-Fe2O3 microspheres consist of well-aligned alpha-Fe2O3 nanoparticles with a mean diameter of about 15 nm. This facile reaction route presents an efficient method for mass production of monodisperse hollow magnetic nanomaterials. The final alpha-Fe2O3 microspheres exhibit special magnetic properties with a small remnant magnetization of 0.09 emu g(-1) and a high coercivity of 1121.67 Oe at room temperature.
引用
收藏
页码:559 / 563
页数:5
相关论文
共 18 条
[1]   Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].
Caruso, F ;
Caruso, RA ;
Möhwald, H .
SCIENCE, 1998, 282 (5391) :1111-1114
[2]   Size Control Synthesis of Uniform β-FeOOH to High Coercive Field Porous Magnetic α-Fe2O3 Nanorods [J].
Chaudhari, Nitin K. ;
Yu, Jong-Sung .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (50) :19957-19962
[3]   Colloidosomes: Selectively permeable capsules composed of colloidal particles [J].
Dinsmore, AD ;
Hsu, MF ;
Nikolaides, MG ;
Marquez, M ;
Bausch, AR ;
Weitz, DA .
SCIENCE, 2002, 298 (5595) :1006-1009
[4]   Nanorods of iron oxalate synthesized using reverse micelles:: Facile route for α-Fe2O3 and Fe3O4 nanoparticles [J].
Ganguli, Ashok K. ;
Ahmad, Tokeer .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2007, 7 (06) :2029-2035
[5]   Single-crystal gallium nitride nanotubes [J].
Goldberger, J ;
He, RR ;
Zhang, YF ;
Lee, SW ;
Yan, HQ ;
Choi, HJ ;
Yang, PD .
NATURE, 2003, 422 (6932) :599-602
[6]   An Assembly Route to Inorganic Catalytic Nanoreactors Containing Sub-10-nm Gold Nanoparticles with Anti-Aggregation Properties [J].
Huang, Xiaoqing ;
Guo, Changyou ;
Zuo, Linquan ;
Zheng, Nanfeng ;
Stucky, Galen D. .
SMALL, 2009, 5 (03) :361-365
[7]   The synthesis and magnetic properties of nanosized hematite (α-Fe2O3) particles [J].
Raming, TP ;
Winnubst, AJA ;
van Kats, CM ;
Philipse, AP .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 249 (02) :346-350
[8]   The crucial role of particle morphology in the magnetic properties of haematite [J].
Sorescu, M ;
Brand, RA ;
Mihaila-Tarabasanu, D ;
Diamandescu, L .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (08) :5546-5548
[9]   Facile route to α-FeOOH and α-Fe2O3 nanorods and magnetic property of α-Fe2O3 nanorods [J].
Tang, B ;
Wang, GL ;
Zhuo, LH ;
Ge, JC ;
Cui, LJ .
INORGANIC CHEMISTRY, 2006, 45 (13) :5196-5200
[10]  
Tian MB, 2001, Magnetic Material