Linking [2]rotaxane wheels to create a new type of metal organic rotaxane framework

被引：43

作者：

Mercer, Darren J. ^{[1
]}

Vukotic, V. Nicholas ^{[1
]}

Loeb, Stephen J. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 03期

关键词：

24-CROWN-8 ETHER WHEELS; CROWN-ETHER; 1,2-BIS(PYRIDINIUM)ETHANE AXLES; LIGANDS; POLYROTAXANES; TEMPLATE; ALCOHOL; ACID;

D O I：

10.1039/c0cc04139d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three new [2]rotaxanes with aromatic nitrogen donors appended to the crown ether wheel have been synthesized and used as ligands to coordinate Cd(II) ions. One of these yields a new type of 2-periodic, metal organic rotaxane framework in which the wheel rather than the axle is used to link the metal nodes.

引用

页码：896 / 898

页数：3

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