Development of High Severity FCC Process for Maximizing Propylene Production - Catalyst Development and Optimization of Reaction Conditions

被引:3
作者
Fujiyama, Yuichiro [1 ]
Al-Tayyar, Mohammad H. [2 ]
Dean, Christopher F. [2 ]
Aitani, Abdullah [3 ]
Redhwi, Halim H. [3 ]
Tsutsui, Toshio [4 ]
Mizuta, Kei [4 ]
机构
[1] JX Nippon Oil & Energy Corp, Chiyoda Ku, Tokyo 1008162, Japan
[2] Saudi Aramco, Dhahran 31311, Saudi Arabia
[3] King Fahd Univ Petr & Minerals, Ctr Refining & Petrochem, Dhahran 31261, Saudi Arabia
[4] Kagoshima Univ, Kagoshima 8908580, Japan
关键词
Fluid catalytic cracking; Propylene; Short contact time; Residue; Zeolite catalyst; Hydrogen transfer; UNIT;
D O I
10.1627/jpi.53.336
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A new hydrocarbon conversion process called High Seventy FCC (HS-FCC) has been developed to maximize propylene production in oil refineries HS-FCC propylene yield was maximized using a combination of three factors catalyst properties reaction conditions and reactor design Optimization of reaction conditions and catalyst development found that high reaction temperature accelerated catalytic cracking rather than hydrogen transfer As a result olefin/paraffin ratio of the product was higher at high reaction temperatures Short contact time suppressed undesirable reactions such as hydrogen transfer and thermal cracking High catalyst/oil (C/O) ratio accelerated catalytic cracking over thermal cracking which also accelerated at high reaction temperatures High C/O ratio is necessary to maintain high reaction temperature by transferring enough heat from regenerator to reactor in commercial FCC units Catalyst properties were investigated to maximize olefin production at high reaction temperatures A proprietary catalyst containing low acid density zeolite suppressed hydrogen transfer and maximized olefin production
引用
收藏
页码:336 / 341
页数:6
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