Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols

被引：30

作者：

Hara, Kenji ^{[1
]}

Tayama, Shinobu ^{[1
]}

Kano, Hidekazu ^{[1
]}

Masuda, Takuya ^{[1
]}

Takakusagi, Satoru ^{[1
]}

Kondo, Toshihiro ^{[1
]}

Uosaki, Kohei ^{[1
]}

Sawamura, Masaya ^{[1
]}

机构：

[1] Hokkaido Univ, Fac Sci, Dept Chem, Sapporo, Hokkaido 0600810, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 41期

关键词：

D O I：

10.1039/b710820f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A single-crystal silicon surface was modified with a bisoxazoline-Pd molecular layer and utilized as a highly efficient (catalyst turnover number up to 780 000, 110 degrees C, 72 h) and recyclable catalyst in the aerobic oxidation of benzylic alcohols.

引用

页码：4280 / 4282

页数：3

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