Improvement of gasification performance of Eucalyptus globulus stumps with torrefaction and densification pre-treatments

被引:56
作者
Pinto, Filomena [1 ]
Gominho, Jorge [2 ]
Andre, Rui Neto [1 ]
Goncalves, David [1 ]
Miranda, Miguel [1 ]
Varela, Francisco [1 ]
Neves, Diogo [1 ]
Santos, Joao [1 ]
Lourenco, Ana [2 ]
Pereira, Helena [1 ]
机构
[1] LNEG, Estr Paco do Lumiar 22, P-1649038 Lisbon, Portugal
[2] Univ Lisbon, Inst Super Agron, Ctr Estudos Florestais, P-1349017 Lisbon, Portugal
关键词
Torrefaction; Densification; Gasification; Eucalyptus globulus; Stumps; THERMODYNAMIC ANALYSIS; BIOMASS GASIFICATION; TORREFIED BIOMASS; CO-GASIFICATION; BEHAVIOR; WASTES; AIR;
D O I
10.1016/j.fuel.2017.06.008
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Eucalyptus globulus stumps has been used as biofuel for energy production. However, forest biomass presents some disadvantages (high moisture, volatiles and oxygen contents, hydrophilic nature, low calorific value, bulk density and energy density). To overcome this, torrefaction and pelletisation were tested. Based on the assays, 250 degrees C and 30 min were selected as the best conditions for the torrefaction. The summative chemical analysis has shown that torrefied stumps presented higher total extractives and lignin content and lower monosaccharides in relation to raw stumps. Eucalyptus stumps were also densified to produce pellets of raw and torrefied material. The materials obtained by the different pre-treatments studied were gasified in a fluidised bed reactor. Gasification gas obtained with raw stumps was compared to those obtained with pre-treated stumps by pelletisation (or densification), torrefaction and torrefaction followed by pelletisation. The results obtained showed that bio-syngas was improved when torrefied biomass was used, as there was an increase in gas yield and CGE (Cold Gas Efficiency) and lower tar were produced. The best pre-treatment for eucalyptus stumps was densification after torrefaction, as at 850 degrees C, gas yield was about 1.22 Nl/g daf and CGE was around 65%. This syngas contained around 38% of H-2, 27% of both CO and CO2 and 5% of CH4. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:289 / 299
页数:11
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