Combustion Properties of Amino-Substituted Guanidinium 4,4′,5,5′-Tetranitro-2,2′-biimidazolate(N4BIM) Salts

被引：7

作者：

Tappan, Bryce C. ^{[1
]}

Chavez, David E. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2015年 / 40卷 / 01期

关键词：

Propellants; Burn rate; High nitrogen; Aminoguanidinium; Tetranitrobiimidazole; ENERGETIC PROPERTIES;

D O I：

10.1002/prep.201400247

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This paper describes the combustion properties of the amino-substituted guanidinium 4,4,5,5-tetranitro-2,2-biimidazolate (N4BIM) series, including the bis-mono, di and triaminoguanidinium salts. These salts are of interest as propellant ingredient additives, and in particular, the bis-triaminoguanidinium salt of N4BIM displays excellent burn rate and combustion behavior. Our combustion studies have shown that TAGN4-BIM displays a fast burning rate and has the lowest pressure dependence exponent yet measured for a triaminoguanidinium salt.

引用

收藏

页码：13 / 15

页数：3

相关论文

共 10 条

[1]

[Anonymous], J PYROTECH

[2]

Bastea S., 2006, CHEETAH USERS MANUAL

[3] Nucleophilic Reactions of The Bis Ammonium Salt of 4,4′,5,5′-Tetranitro-2,2′-biimidazole [J].

Breiner, Megan M. ;

Chavez, David E. ;

Parrish, Damon A. .

SYNLETT, 2013, 24 (04) :519-521

[4] SYNTHESIS AND COMBUSTION CHARACTERISTICS OF NOVEL HIGH-NITROGEN MATERIALS [J].

Chavez, David E. ;

Tappan, Bryce C. .

INTERNATIONAL JOURNAL OF ENERGETIC MATERIALS AND CHEMICAL PROPULSION, 2013, 12 (02) :173-182

[5] Synthesis and Energetic Properties of 4,4′,5,5′-Tetranitro-2,2′-biimidazolate(N4BIM) Salts [J].

Chavez, David E. ;

Parrish, Damon ;

Preston, Daniel N. ;

Mares, Isaac W. .

PROPELLANTS EXPLOSIVES PYROTECHNICS, 2012, 37 (06) :647-652

[6] Synthesis and Energetic Properties of Bis-(Triaminoguanidinium) 3,3′-Dinitro-5,5′-Azo-1,2,4-Triazolate (TAGDNAT): A New High-Nitrogen Material [J].

Chavez, David E. ;

Tappan, Bryce C. ;

Mason, Benjamin Aaron ;

Parrish, Damon .

PROPELLANTS EXPLOSIVES PYROTECHNICS, 2009, 34 (06) :475-479

[7] New high-nitrogen materials based on nitroguanyl-tetrazines: Explosive properties, thermal decomposition and combustion studies [J].

Chavez, DE ;

Tappan, BC ;

Hiskey, MA ;

Son, SF ;

Harry, H ;

Montoya, D ;

Hagelberg, S .

PROPELLANTS EXPLOSIVES PYROTECHNICS, 2005, 30 (06) :412-417

[8]

Kim J.K., 2012, US Patent Appl., Patent No. [US20120203008, 20120203008]

[9] High Nitrogen Energetic Salts of 4,4′,5,5′-Tetranitro-2,2′-Biimidazole [J].

Kim, Seung Hee ;

Kim, Jin Seuk .

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2013, 34 (08) :2503-2506

[10] Energetic Derivatives of 4, 4′,5, 5′-Tetranitro-2, 2′-bisimidazole (TNBI) [J].

Klapoetke, Thomas M. ;

Preimesser, Andreas ;

Stierstorfer, Joerg .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (09) :1278-1286