A study on preparation and characteristic of RuO2/TiO2 coupled photocatalyst

被引:0
作者
Yao, BH [1 ]
Wang, LM
Yu, XJ
Yang, GN
Zhao, GY
Zheng, HL
机构
[1] Xian Univ Technol, Dept Appl Chem, Xian 710048, Peoples R China
[2] Chongqing Univ, Coll Chem & Chem Engn, Chongqing 400044, Peoples R China
关键词
photocatalytic reaction; photocatalyst; titanium dioxide; dye; direct fast black G;
D O I
暂无
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
RuO2/TiO2 coupled photocatalyst was prepared by sol-gel-dipping method. Being a model reaction, the photocatalytic degradation of direct fast black G was investigated in RuO2/TiO2 powder suspension irradiated by UV-lamp. The results showed that the addition of RuO2 to TiO2 greatly enhanced its photocatalytic activity, and the optimum dipped content of RuO2 was 0. 16%, the optimum value of the calcinations temperature and the addition of RuO2 /TiO2 powder were 500 degrees C and 5. 00 g.L-1, respectively. The photocatalytic degradation of direct fast black G was experimentally demonstrated to follow the Langmuir-Hinshelwood kinetic model, and the adsorption constant ( 14.22 L.mmol(-1)) and the reaction rate constant [4.94 x 10(-3) mmol(L.min)(-1)] were determined, respectively.
引用
收藏
页码:934 / 937
页数:4
相关论文
共 9 条
[1]   FTIR study of the photocatalytic degradation of NH4+ determination wastes [J].
Araña, J ;
Rendón, ET ;
Rodríguez, JMD ;
Melián, JAH ;
Díaz, OG ;
Peña, JP .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) :215-222
[2]   Modeling the photocatalytic degradation of formic acid in a reactor with immobilized catalyst [J].
Dijkstra, MFJ ;
Panneman, HJ ;
Winkelman, JGM ;
Kelly, JJ ;
Beenackers, AACM .
CHEMICAL ENGINEERING SCIENCE, 2002, 57 (22-23) :4895-4907
[3]  
HOFFMAN MR, 1995, CHEM REV, V95, P1
[4]   The effect of operational parameters and TiO2-doping on the photocatalytic degradation of azo-dyes [J].
Kiriakidou, F ;
Kondarides, DI ;
Verykios, XE .
CATALYSIS TODAY, 1999, 54 (01) :119-130
[5]   An investigation on photocatalytic activities of mixed TiO2-rare earth oxides for the oxidation of acetone in air [J].
Lin, J ;
Yu, JC .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1998, 116 (01) :63-67
[6]   Photocatalytic oxidation of methyl orange in a three-phase fluidized bed reactor [J].
Nam, W ;
Kim, J ;
Han, GY .
CHEMOSPHERE, 2002, 47 (09) :1019-1024
[7]   Comparison of photocatalytic efficiencies of TiO2 in suspended and immobilised form for the photocatalytic degradation of nitrobenzenesulfonic acids [J].
Rachel, A ;
Subrahmanyam, M ;
Boule, P .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 37 (04) :301-308
[8]  
Ye Z, 2002, SPECTROSC SPECT ANAL, V22, P928
[9]  
于向阳, 2000, [华东理工大学学报. 自然科学版, Journal of East China University of Science and Technoloy. Natural Sciences Edition], V26, P287