Chlorination of secondary phosphine chalcogenides with carbon tetrachloride in the absence of bases

被引：3

作者：

Gusarova, N. K. ^{[1
]}

Volkov, P. A. ^{[1
]}

Ivanova, N. I. ^{[1
]}

Khrapova, K. O. ^{[1
]}

Trofimov, B. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Favorskii Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 02期

关键词：

secondary phosphine chalcogenide; carbon tetrachloride; chlorophosphine chalcogenide; PHOSPHINOCHALCOGENOIC AMIDATO COMPLEXES; DERIVATIVES; LIGANDS; METALS;

D O I：

10.1134/S107036321502005X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interaction of bis(2-phenylethyl)phosphine sulfide, bis(2-phenylethyl)phosphine selenide and bis[2-(2-phenyl)propyl]phosphine selenide with carbon tetrachloride under heating (80A degrees C, 8-20 h) leads to the formation of the corresponding chlorophosphine chalcogenides with the yield of 80-90%.

引用

页码：380 / 382

页数：3