Raman spectroscopy of n-pentyl methyl ether and deuterium labelled analogues

被引：7

作者：

Bowen, Richard D. ^{[1
]}

Edwards, Howell G. M. ^{[1
]}

Farwell, Dennis W. ^{[1
]}

Morgan, Sara E. ^{[1
]}

机构：

[1] Univ Bradford, Sch Life Sci, Bradford BD7 1DP, W Yorkshire, England

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 2010年 / 41卷 / 12期

关键词：

pentyl; ether; deuterium labelling; vibrational assignments; SPECTRA;

D O I：

10.1002/jrs.2595

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Raman spectra of n-pentyl methyl ether, C(5)H(11)OCH(3), and six selectively deuteriated analogues are reported and discussed. Correlations between the observed v(sp(3)CH) stretching and bending bands and the position of the deuterium atoms in the alkyl chain are developed and refined. Similar progress is possible in associating specific skeletal vibrations with bands in the Raman spectra. The relevance of this study to improving the assignment of bands in the Raman spectra of larger systems of biological interest is highlighted. Copyright (C) 2010 John Wiley & Sons, Ltd.

引用

页码：1725 / 1734

页数：10

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