Recent Advances of Catalytic Effects in Cathode Materials for Room-Temperature Sodium-Sulfur Batteries

被引：12
作者：
Li, Sijie [2 ,4 ]
Han, Yu [3 ]
Ge, Peng [1 ]
Yang, Yue [1 ]
机构：
[1] Cent South Univ, Sch Resource Proc & Bioengn, Changsha 410083, Peoples R China
[2] Hokkaido Univ, Grad Sch Chem Sci & Engn, Sapporo, Hokkaido 0600814, Japan
[3] China Three Gorges Corp, Inst Sci & Technol, Comprehens Energy Res Ctr, Beijing 100038, Peoples R China
[4] Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, Tsukuba, Ibaraki 3050044, Japan
来源：
CHEMPLUSCHEM | 2021年 / 86卷 / 10期
基金：
中国国家自然科学基金;
关键词：
cathode materials; electrocatalysts; energy storage; kinetics; room-temperature sodium-sulfur batteries; LI-S BATTERY; CHALLENGES; POLYSULFIDES; COMPOSITES; ELECTRODE; DESIGN;
D O I：
10.1002/cplu.202100328
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electrocatalysts in room-temperature sodium-sulfur (RT-Na/S) have captured numerous attention. But, they suffered from shuttle effect and surface passivation. RT-Na/S show inferior energy-storage abilities, ascribed to the larger radii of Na-ions. Herein, the vigorous review is displayed from different kinds of metal-based traits, containing single metal, metal-based samples, and multifunctional hybrids. Through the controlling of structures and composition, the conversion reaction about liquid/solid phases would be enhanced, accompanied by the enhancements of cycling stabilities and rate properties, which enables the break-through of practical applications. The in-depth influences of catalytic effects on the Na-S reaction mechanism and the corresponding electrochemical performance in recently representative works are systematically reviewed. Particularly, this review is anticipated to propose potential research directions for further enhancement of RT-Na/S batteries.
引用
收藏
页码：1461 / 1471
页数：11
相关论文
共 49 条
[21]   Macro-microporous carbon with a three-dimensional channel skeleton derived from waste sunflower seed shells for sustainable room-temperature sodium sulfur batteries [J].
Liu, Ying ;
Li, Xueying ;
Sun, Yuanzheng ;
Yang, Rong ;
Lee, Younki ;
Ahn, Jou-Hyeon .
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 853
[22]   Dual Play of Chitin-Derived N-Doped Carbon Nanosheets Enabling High-Performance Na-SeS2 Half/Full Cells [J].
Ma, Jingqi ;
Gao, Lingfeng ;
Li, Shuping ;
Zeng, Ziqi ;
Zhang, Lina ;
Xie, Jia .
BATTERIES & SUPERCAPS, 2020, 3 (02) :165-173
[23]   Multi-step Controllable Catalysis Method for the Defense of Sodium Polysulfide Dissolution in Room-Temperature Na-S Batteries [J].
Ma, Qianru ;
Zhong, Wei ;
Du, Guangyuan ;
Qi, Yuruo ;
Bao, Shu-Juan ;
Xu, Maowen ;
Li, Changming .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (10) :11852-11860
[24]   Carbon-wrapped cobalt nanoparticles on graphene aerogel for solid-state room sodium-sulfur batteries [J].
Ma, Qianru ;
Du, Guangyuan ;
Guo, Bingshu ;
Tang, Wenwen ;
Li, Yutao ;
Xu, Maowen ;
Li, Changming .
CHEMICAL ENGINEERING JOURNAL, 2020, 388
[25]   Ambient Temperature Sodium-Sulfur Batteries [J].
Manthiram, Arumugam ;
Yu, Xingwen .
SMALL, 2015, 11 (18) :2108-2114
[26]   Sulfur-Rich Molybdenum Sulfide as a Cathode Material for Room Temperature Sodium-Sulfur Batteries [J].
Meyerson, Melissa L. ;
Papa, Philippe E. ;
Weeks, Jason A. ;
Paul-Orecchio, Austin G. ;
Heller, Adam ;
Mullins, C. Buddie .
ACS APPLIED ENERGY MATERIALS, 2020, 3 (07) :6121-6126
[27]   Hierarchical porous carbon sheets for high-performance room temperature sodium-sulfur batteries: integration of nitrogen-self-doping and space confinement [J].
Mou, Jirong ;
Liu, Ting ;
Li, Yijuan ;
Zhang, Wenjia ;
Li, Mei ;
Xu, Yuting ;
Huang, Jianlin ;
Liu, Meilin .
JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (46) :24590-24597
[28]   High and intermediate temperature sodium-sulfur batteries for energy storage: development, challenges and perspectives [J].
Nikiforidis, Georgios ;
van de Sanden, M. C. M. ;
Tsampas, Michail N. .
RSC ADVANCES, 2019, 9 (10) :5649-5673
[29]   Carbon/Sulfur Composites Stabilized with Nano-TiNi for High-Performance Li-S Battery Cathodes [J].
Pang, Yuepeng ;
Xu, Ying ;
Li, Yongtao ;
Xu, Fen ;
Sun, Lixian ;
Yang, Junhe ;
Li, Hai-Wen ;
Zheng, Shiyou .
ACS APPLIED ENERGY MATERIALS, 2019, 2 (02) :1537-1543
[30]   High performance room temperature Na-S batteries based on FCNT modified Co3C-Co nanocubes [J].
Qin, Guohui ;
Liu, Yuting ;
Han, Pinyu ;
Cao, Shixun ;
Guo, Xinyu ;
Guo, Ziyang .
CHEMICAL ENGINEERING JOURNAL, 2020, 396
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