Improvement of mechanical, morphological and thermal properties on PP-enriched graphene oxide/PP-g-MA/EPDM blend compatibilized: PP-g-MA compatibilizer and graphene oxide nanofiller role

被引:16
作者
Azizli, Mohammad Javad [1 ]
Barghamadi, Mohammad [2 ]
Rezaeeparto, Katayoon [3 ]
Parham, Somayeh [3 ]
机构
[1] Islamic Azad Univ, Dept Chem & Chem Engn, Rasht Branch, Rasht, Iran
[2] Iran Polymer & Petrochem Inst, Tehran 14965115, Iran
[3] Res Inst Petr Ind, Tehran 1485733111, Iran
关键词
Graphene oxide; GO-PP; PP-g-MA; EPDM; Mechanical properties; Christensen-Lo theory; Creep behaviour; CHRISTENSEN-LO MODEL; INTERPHASE; NANOPARTICLES; COMPOSITE; TOUGHNESS; STRENGTH; MATRIX; MODULI;
D O I
10.1007/s10965-022-03182-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
One of the modern methods of mixing polymers that causes the properties of nanocomposites to be significantly improved is the incorporation of nanofillers into the matrix. In this study, polypropylene (PP) was reinforced using graphene oxide and then PP-g-MA compatibilizer was used for better dispersion of graphene oxide and compatibility between polypropylene and ethylene-propylene rubber (EPDM). The purpose of this study is to achieve the optimum blend composition. In this regard, the mechanical, rheological and morphological properties of samples using DMTA, TGA and DSC were examined and their theory was analyzed. The results showed that the mechanical properties such as tensile strength, elongation at break and young's modulus are significantly improved by increasing the concentration of graphene oxide in the presence of PP-g-MA compatibilizer. SEM images also illustrated that with the increasing concentration of nanofillers in the blend matrix, the particle size of the dispersed phase of EPDM decreases. In addition, TEM images also showed the presence of PP-g-MA compatibilizer causing better dispersion of graphene oxide in GO-PP/ PP-g-MA/EPDM nanocomposites.
引用
收藏
页数:16
相关论文
共 45 条
[1]   Investigation of the rutting potential of asphalt binder and mixture modified by styrene-ethylene/propylene-styrene nanocomposite [J].
Azarhoosh, Alireza ;
Koohmishi, Mehdi .
CONSTRUCTION AND BUILDING MATERIALS, 2020, 255
[2]   Graphene oxide and graphene hybrid nanocomposites based on compatibilized PP/PTW/EVA: effect of nanofiller and compatibilizer on the modeling of viscoplastic behavior [J].
Azizl, Mohammad Javad ;
Barghamadi, Mohammad ;
Rezaeeparto, Katayoon ;
Mokhtary, Masoud ;
Parham, Somayeh .
JOURNAL OF POLYMER RESEARCH, 2021, 28 (08)
[3]   Compatibility, mechanical and rheological properties of hybrid rubber NR/EPDM-g-MA/EPDM/graphene oxide nanocomposites: Theoretical and experimental analyses [J].
Azizli, Mohammad Javad ;
Barghamadi, Mohammad ;
Rezaeeparto, Katayoon ;
Mokhtary, Masoud ;
Parham, Somayeh .
COMPOSITES COMMUNICATIONS, 2020, 22
[4]   Enhancement of thermal, morphological, and mechanical properties of compatibilized based onPA6-enriched graphene oxide/EPDM-g-MA/CR: Graphene oxide andEPDM-g-MAcompatibilizer role [J].
Azizli, Mohammad Javad ;
Barghamadi, Mohammad ;
Rezaeeparto, Katayoon ;
Mokhtary, Masoud ;
Parham, Somayeh ;
Goodarzi, Vahabodin ;
Soltani, Sedigheh .
JOURNAL OF APPLIED POLYMER SCIENCE, 2021, 138 (09)
[5]   Modeling of nonlinearhyper-viscoelasticand stress softening behaviors of acrylonitrile butadiene rubber/polyvinyl chloride nanocomposites reinforced by nanoclay and graphene [J].
Barghamadi, Mohammad ;
Ghoreishy, Mir Hamid Reza ;
Karrabi, Mohammad ;
Mohammadian-Gezaz, Somayyeh .
POLYMER COMPOSITES, 2021, 42 (02) :583-596
[6]   Investigation on the kinetics of cure reaction of acrylonitrile-butadiene rubber (NBR)/polyvinyl chloride (PVC)/graphene nanocomposite using various models [J].
Barghamadi, Mohammad ;
Ghoreishy, Mir Hamid Reza ;
Karrabi, Mohammad ;
Mohammadian-Gezaz, Somayyeh .
JOURNAL OF APPLIED POLYMER SCIENCE, 2020, 137 (18)
[7]   Effects of two types of nanoparticles on the cure, rheological, and mechanical properties of rubber nanocomposites based on the NBR/PVC blends [J].
Barghamadi, Mohammad ;
Karrabi, Mohammad ;
Ghoreishy, Mir Hamid Reza ;
Mohammadian-Gezaz, Somayyeh .
JOURNAL OF APPLIED POLYMER SCIENCE, 2019, 136 (25)
[8]   Investigation of rheological, mechanical, and thermal properties of nanocomposites based on nitrile rubber-phenolic resin reinforced with nanographene [J].
Bazli, Leila ;
Barghamadi, Mohammad ;
Shafiee, Sara ;
Karrabi, Mohammad ;
Ghoreishy, Mir Hamid Reza .
JOURNAL OF APPLIED POLYMER SCIENCE, 2021, 138 (36)
[9]   In situ tuning of graphene oxide morphology by electrochemical exfoliation [J].
Biranje, Pratiksha M. ;
Prakash, Jyoti ;
Srivastava, Amit P. ;
Biswas, Sujoy ;
Patwardhan, Ashwin W. ;
Joshi, Jyeshtharaj B. ;
Dasgupta, Kinshuk .
JOURNAL OF MATERIALS SCIENCE, 2021, 56 (35) :19383-19402
[10]   ON ELASTIC MODULI OF SOME HETEROGENEOUS MATERIALS [J].
BUDIANSK.B .
JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 1965, 13 (04) :223-&