An 18+δ iridium dimer releasing metalloradicals spontaneously

被引：10

作者：

Chen, Tsun-Ren ^{[1
]}

Lee, Hsiu-Pen ^{[1
]}

Chen, Jhy-Der ^{[2
]}

Chen, Kelvin H. -C. ^{[1
]}

机构：

[1] Natl Pingtung Univ Educ, Dept Biol Chem, Pingtung 90003, Taiwan

[2] Chung Yuan Christian Univ, Dept Chem, Chungli 32023, Taiwan

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 40期

关键词：

X-RAY-ABSORPTION; ELECTROCHEMICAL PROPERTIES; BOND ACTIVATION; COMPLEXES; ELECTRON; REACTIVITY; DNA; METAL; SUBSTITUTION; MANIPULATION;

D O I：

10.1039/c0dt00605j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reductive elimination of a bridged chlorine from a diiridium(III) core, [(dfpbo)(2)Ir(mu-Cl)](2) (dfpbo = 2-(3.5-difluorophenyl) benzoxazolato-N,C(2)), afforded an iridium dimer, [(fpbo)(2)Ir](2)(mu-Cl), showing an 18+delta structure with a bent bridge, which can release metalloradicals spontaneously in solution at room temperature.

引用

页码：9458 / 9461

页数：4

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