Visible-Light-Induced 3-Component Synthesis of Sulfonylated Oxindoles by Fixation of Sulfur Dioxide

被引：37

作者：

Liu, Nai-Wei ^{[1
]}

Chen, Zhengkai ^{[2
]}

Herbert, Andre ^{[1
]}

Ren, Hongjun ^{[2
]}

Manolikakes, Georg ^{[1
,3
]}

机构：

[1] Goethe Univ Frankfurt, Inst Organ Chem & Chem Biol, Max Von Laue Str 7, D-60438 Frankfurt, Germany

[2] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China

[3] TU Kaiserslautern, Dept Chem, Erwin Schrodinger Str Geb 54, D-67663 Kaiserslautern, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 2018卷 / 41期

基金：

中国国家自然科学基金;

关键词：

Sulfur dioxide; Sulfones; Photochemistry; Nitrogen heterocycles; Hypervalent compounds; ONE-POT SYNTHESIS; PALLADIUM-CATALYZED AMINOSULFONYLATION; METAL-FREE SYNTHESIS; C-H FUNCTIONALIZATION; DIARYLIODONIUM SALTS; N-ARYLACRYLAMIDES; ORGANOMETALLIC REAGENTS; MULTICOMPONENT REACTION; SULFONATED OXINDOLES; ARYLBORONIC ACIDS;

D O I：

10.1002/ejoc.201801128

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel, visible-light-induced 3-component synthesis of sulfonylated oxindoles from N-arylacrylamides, diaryliodonium salts and sulfur dioxide is described. The reaction provides simple access to a wide variety of 3-[(arylsulfonyl)methyl]indolin-2-ones in moderate to excellent yields under mild conditions at room temperature. The transformation proceeds in the absence of any external photosensitizer and enables an efficient, solely visible-light-driven fixation of sulfur dioxide.

引用

页码：5725 / 5734

页数：10

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