Comparison of photocatalytic activities of two kinds of lead magnesium niobate for decomposition of organic compounds under visible-light irradiation

被引:11
作者
Kako, Tetsuya [1 ]
Ye, Jinhua [1 ]
机构
[1] Natl Inst Mat Sci, Photocatalyt Mat Ctr, Tsukuba, Ibaraki 3050047, Japan
关键词
D O I
10.1557/JMR.2007.0333
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Two new oxide photocatalysts in the Pb-Mg-Nb ternary system, Pb3MgNb2O9 (PMN) and Pb-1.83 mg(0.29)Nb(1.71)O(6.39), have been synthesized, and their photophysical and photocatalytic properties were investigated for the first time. The band gaps of PMN and Pb1.83Mg0.29Nb1.71O6.39 were estimated to be 3.2 and 2.8 eV, respectively, from their absorption spectra. The photocatalytic activity evaluated from the decomposition of 2-propanol into acetone under visible-light irradiation indicated that Pb1.83Mg0.29Nb1.71O6.39, exhibited at least 20 times higher activity than PMN and has a strong oxidizing potential to mineralize organic compounds.
引用
收藏
页码:2590 / 2597
页数:8
相关论文
共 37 条
[1]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[2]   Preparation, testing and characterization of doped TiO2 active in the peroxidation of biomolecules under visible light [J].
Bacsa, R ;
Kiwi, J ;
Ohno, T ;
Albers, P ;
Nadtochenko, V .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (12) :5994-6003
[3]   THE CRYSTAL-STRUCTURES OF PYROCHLOVE TYPE LEAD NIOBATE [J].
BERNOTATWULF, H ;
HOFFMANN, W .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1982, 158 (1-2) :101-117
[4]   Electronic structure of the ferroelectric-layered perovskite bismuth titanate by ab initio calculation within density functional theory [J].
Cai, MQ ;
Yin, Z ;
Zhang, MS ;
Li, YZ .
CHEMICAL PHYSICS LETTERS, 2004, 399 (1-3) :89-93
[5]   THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS [J].
CHOI, WY ;
TERMIN, A ;
HOFFMANN, MR .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) :13669-13679
[6]   Observations on structural evolution and dielectric properties of oxygen-deficient pyrochlores [J].
Du, HL ;
Wang, H ;
Yao, X .
CERAMICS INTERNATIONAL, 2004, 30 (07) :1383-1387
[7]   Evaluation of Bi-W-oxides for visible light photocatalysis [J].
Finlayson, AP ;
Tsaneva, VN ;
Lyons, L ;
Clark, M ;
Glowacki, BA .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2006, 203 (02) :327-335
[8]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[9]   Carbon-doped anatase TiO2 powders as a visible-light sensitive photocatalyst [J].
Irie, H ;
Watanabe, Y ;
Hashimoto, K .
CHEMISTRY LETTERS, 2003, 32 (08) :772-773
[10]   Oxysulfides Ln2Ti2S2O5 as stable photocatalysts for water oxidation and reduction under visible-light irradiation [J].
Ishikawa, A ;
Takata, T ;
Matsumura, T ;
Kondo, JN ;
Hara, M ;
Kobayashi, H ;
Domen, K .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (08) :2637-2642