Influence of electric field and emission current on the configuration of nanotubes in carbon nanotube layers

The influence of applied electric field (E-av) and emission current (I-FE) on the configuration of conical layers carbon nanotubes (CLNTs) grown by CVD on the edge of Ni foil has been investigated. TEM profile imaging revealed a high concentration of nanotubes near the foil edge surface, whereas on the nanotube layers' outer surfaces single, non-oriented nanotubes with open ends free of catalytic particles, were observed. After sufficient electric field application many nanotubes became oriented towards the anode, but one or two of them were round to be always a few,, microns more extended. In situ SEM investigation showed that below E-av = 3.2-3.9 V/mu m, emission was achieved at the expense (if originally existing free nanotube end. Configuration changes began at larger electric fields. On the observed foil edge length (14.6 17.8 mu m, with in edge thickness of 200 mu m) one or two nanotubes extended towards the anode and probably became the main emitters, Upon further increasing the field to E-av, 5.7 8 V/mu m and at an emission current I-FE = 2 x 10(-5) A these tubes disappeared for essentially shortened). At E-av -8 V/mu m and higher and at an exposure time up to 40 min, several tens of extended nanotubes appeared, with one or two extended well beyond the others. This nanotube configuration pattern is connected with electrostatic screening between the nanotubes, Our interpretation of the data suggests that in the investigated range of E-av and I-FE, a limited number of nanotubes are emitting and these nanotubes are constantly changing as E-av, I-FE and exposure time increase. (C) 2005 Elsevier Ltd. All rights reserved.