Two new one-dimensional coordination polymers containing [N(CN)2]- - Syntheses, structures, and magnetic properties of [MII(3-Bzpy)2(N(CN)2)2](M = Mn (1) and Co (2) and 3-Bzpy=3-benzoylpyridine)

被引：1

作者：

Bao, Qianqian ^{[1
]}

Ma, Yutao ^{[2
]}

Zhao, Qihua ^{[2
]}

Luo, Yanghui ^{[1
]}

Sun, Baiwang ^{[1
]}

机构：

[1] Southeast Univ, Dept Chem & Chem Engn, Ordered Matter Sci Res Ctr, Nanjing 210096, Jiangsu, Peoples R China

[2] Yunnan Univ, Minist Educ, Dept Chem, Key Lab Med Chem Nat Resource, Kunming 650091, Peoples R China

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2012年 / 90卷 / 04期

基金：

中国国家自然科学基金;

关键词：

dicyanamide; 1-D; structure; magnetic property; BRIDGING LIGAND; DICYANAMIDE; DCA; NI;

D O I：

10.1139/V2012-004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures of two one-dimensional coordination complexes, [M-II(3-Bzpy)(2)(N(CN)(2))(2)] (M = Mn (1) and Co (2) and 3-Bzpy = 3-benzoylpyridine), have been determined in this work. The two structures are isomorphous, crystallize in a monoclinic P2(1)/c space group, and show almost the same crystal structure. The magnetic measurements of the two compounds (2-300 K) indicate that antiferromagnetic exchanges exist between the metal ions of the two compounds.

引用

页码：362 / 367

页数：6