Two new one-dimensional coordination polymers containing [N(CN)2]- - Syntheses, structures, and magnetic properties of [MII(3-Bzpy)2(N(CN)2)2](M = Mn (1) and Co (2) and 3-Bzpy=3-benzoylpyridine)

被引:1
作者
Bao, Qianqian [1 ]
Ma, Yutao [2 ]
Zhao, Qihua [2 ]
Luo, Yanghui [1 ]
Sun, Baiwang [1 ]
机构
[1] Southeast Univ, Dept Chem & Chem Engn, Ordered Matter Sci Res Ctr, Nanjing 210096, Jiangsu, Peoples R China
[2] Yunnan Univ, Minist Educ, Dept Chem, Key Lab Med Chem Nat Resource, Kunming 650091, Peoples R China
基金
中国国家自然科学基金;
关键词
dicyanamide; 1-D; structure; magnetic property; BRIDGING LIGAND; DICYANAMIDE; DCA; NI;
D O I
10.1139/V2012-004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structures of two one-dimensional coordination complexes, [M-II(3-Bzpy)(2)(N(CN)(2))(2)] (M = Mn (1) and Co (2) and 3-Bzpy = 3-benzoylpyridine), have been determined in this work. The two structures are isomorphous, crystallize in a monoclinic P2(1)/c space group, and show almost the same crystal structure. The magnetic measurements of the two compounds (2-300 K) indicate that antiferromagnetic exchanges exist between the metal ions of the two compounds.
引用
收藏
页码:362 / 367
页数:6
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