Kinetic effects of tartaric acid on the growth of chiral J-aggregates of tetrakis(4-sulfonatophenyl)porphyrin

被引:44
作者
Castriciano, Maria Angela [1 ]
Romeo, Andrea [1 ,2 ,3 ]
Zagami, Roberto [2 ,3 ]
Micali, Norberto [4 ]
Scolaro, Luigi Monsu [1 ,2 ,3 ]
机构
[1] CNR ISMN, Ist Studio Mat Nanostrutturati, I-98166 Messina, Italy
[2] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy
[3] Univ Messina, CIRCMSB, I-98166 Messina, Italy
[4] CNR IPCF, Ist Proc Chim Fis, I-98158 Messina, Italy
关键词
2-PHOTON ABSORPTION; PORPHYRIN; WATER; SCATTERING; ASSEMBLIES; COMPLEXES; SPECTRA; SIZE;
D O I
10.1039/c2cc00028h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The kinetics of growth for chiral J-aggregates of H4TPPS4 porphyrin have been investigated under different experimental conditions in the presence of tartaric acid. The observed rate constants and the anisotropy factor g show a defined dependence on the enantiomer used as a chiral templating agent.
引用
收藏
页码:4872 / 4874
页数:3
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