Cobalt(II), nickel(II) and copper(II) complexes of a Schiff base ligand: synthesis, structural characterization and luminescence properties

被引：15

作者：

Gonul, Ilyas ^{[1
]}

Faki, Ender ^{[1
]}

Ay, Burak ^{[1
]}

Kose, Muhammet ^{[2
]}

Serin, Selahattin ^{[1
]}

机构：

[1] Cukurova Univ, Arts & Sci Fac, Dept Chem, TR-01330 Adana, Turkey

[2] Kahramanmaras Sutcu Imam Univ, Dept Chem, TR-46100 Kahramanmaras, Turkey

来源：

TRANSITION METAL CHEMISTRY | 2018年 / 43卷 / 01期

关键词：

TRANSITION-METAL-COMPLEXES; RAY CRYSTAL-STRUCTURES; NI(II) COMPLEXES; SPECTROSCOPIC CHARACTERIZATION; ZINC(II) COMPLEXES; DNA CLEAVAGE; PHOTOLUMINESCENCE; CU(II); VANADIUM(IV); ANTIOXIDANT;

D O I：

10.1007/s11243-017-0195-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Schiff base ligand (HL), 2,4-dimethoxy-N-(5-chloro-2-hydroxybenzylidene)-benzenamine, derived from 5-chloro-2-hydroxybenzaldehyde and 2,4-dimethoxyaniline, and its metal complexes [Co(L)(2)]center dot CH3OH (1), [Ni(L)(2)] (2), [Cu(L)(2)] (3) have been synthesized. The compounds were characterized by analytical and spectroscopic methods. In addition, the structures of the Schiff base HL and its Co(II) complex were determined by single-crystal X-ray analysis. The Co(II) center is six-coordinate, being coordinated to two imine nitrogen, two phenolate oxygen and two methoxy oxygen atoms of two crystallographically independent Schiff base ligands. Luminescence properties of HL and its complexes were investigated both in solution and in the solid state.

引用

页码：73 / 81

页数：9

共 34 条

[11] Structural characterization and electrochemical studies of Co(II), Zn(II), Ni(II) and Cu(II) Schiff base complexes derived from 2-((E)-(2-methoxyphenylimino)methyl)-4-bromophenol; Evaluation of antioxidant and antibacterial properties [J].

Galini, Masumeh ;

Salehi, Mehdi ;

Kubicki, Maciej ;

Amiri, Ahmad ;

Khaleghian, Ali .

INORGANICA CHIMICA ACTA, 2017, 461 :167-173

[12] Recognition of fluoride anions at low ppm level inside living cells and from fluorosis affected tooth and saliva samples [J].

Ghosh, Pritam ;

Roy, Biswajit Gopal ;

Mukhopadhyay, Subhra Kanti ;

Banerjee, Priyabrata .

RSC ADVANCES, 2015, 5 (35) :27387-27392

[13] Synthesis, characterization, crystal structure determination and computational study of a new Cu(II) complex of bis [2-{(E)-[2-chloroethyl)imino]methyl}phenolato)] copper(II) Schiff base complex [J].

Grivani, Gholamhossein ;

Vakili, Mohammad ;

Khalaji, Aliakbar Dehno ;

Bruno, Giuseppe ;

Rudbari, Hadi Amiri ;

Taghavi, Maedeh .

JOURNAL OF MOLECULAR STRUCTURE, 2016, 1116 :333-339

[14]

Hariprasath K., 2012, J CHEM PHARM RES, V2, P496

[15] Synthesis, structures and urease inhibitory activity of cobalt(III) complexes with Schiff bases [J].

Jing, Changling ;

Wang, Cunfang ;

Yan, Kai ;

Zhao, Kedong ;

Sheng, Guihua ;

Qu, Dan ;

Niu, Fang ;

Zhu, Hailiang ;

You, Zhonglu .

BIOORGANIC & MEDICINAL CHEMISTRY, 2016, 24 (02) :270-276

[16] Synthesis, spectral characterisation, morphology, biological activity and DNA cleavage studies of metal complexes with chromone Schiff base [J].

Kavitha, P. ;

Reddy, K. Laxma .

ARABIAN JOURNAL OF CHEMISTRY, 2016, 9 (04) :596-605

[17] Synthesis, characterization and X-ray crystal structures of Vanadium(IV), Cobalt(III), Copper(II) and Zinc(II) complexes derived from an asymmetric bidentate Schiff-base ligand at ambient temperature [J].

Khorshidifard, Mahsa ;

Rudbari, Hadi Amiri ;

Kazemi-Delikani, Zahra ;

Mirkhani, Valiollah ;

Azadbakht, Reza .

JOURNAL OF MOLECULAR STRUCTURE, 2015, 1081 :494-505

[18] Evaluation of DNA cleavage, antimicrobial and anti-tubercular activities of potentially active transition metal complexes derived from 2,6-di(benzofuran-2-carbohydrazono)-4-methylphenol [J].

Kokare, Dhoolesh Gangaram ;

Kamat, Vinayak ;

Naik, Krishna ;

Nevrekar, Anupama ;

Kotian, Avinash ;

Revankar, Vidyanand K. .

JOURNAL OF MOLECULAR STRUCTURE, 2017, 1127 :289-295

[19] Monodentate Schiff base ligands: Their structural characterization, photoluminescence, anticancer, electrochemical and sensor properties [J].

Kose, Muhammet ;

Ceyhan, Gokhan ;

Tumer, Mehmet ;

Demirtas, Ibrahim ;

Gonul, Ilyas ;

Mckee, Vickie .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 137 :477-485

[20] Synthesis, crystal structure and photophysical properties of (E)-4-(4-(2-hydroxybenzylideneamino)benzyl)oxazolidin-2-one [J].

Kumari, Rekha ;

Varghese, Anitha ;

George, Louis .

JOURNAL OF LUMINESCENCE, 2016, 179 :518-526

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