Alternating Copolymerization of Epoxides and Anhydrides Catalyzed by Aluminum Complexes

被引：27
作者：
de Sarasa Buchaca, Marc Martinez [1 ]
de la Cruz-Martinez, Felipe [1 ]
Martinez, Javier [2 ]
Alonso-Moreno, Carlos [3 ]
Fernandez-Baeza, Juan [1 ]
Tejeda, Juan [1 ]
Niza, Enrique [3 ]
Castro-Osma, Jose A. [3 ]
Otero, Antonio [1 ]
Lara-Sanchez, Agustin [1 ]
机构：
[1] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Ctr Innovac Quim Avanzada ORFEO CINQA, Fac Ciencias & Tecnol Quim, E-13071 Ciudad Real, Spain
[2] Univ Catolica Chile, Lab Quim Inorgan, Fac Quim, Casilla 306, Santiago 6094411 22, Chile
[3] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Ctr Innovac Quim Avanzada ORFEO CINQA, Fac Farm, Albacete 02071, Spain
来源：
ACS OMEGA | 2018年 / 3卷 / 12期
关键词：
RING-OPENING POLYMERIZATION; CYCLIC ANHYDRIDES; BONDING ORGANOCATALYSTS; EPSILON-CAPROLACTONE; CARBON-DIOXIDE; ZINC; POLYESTERS; ESTERS; REACTIVITY; POLYMERS;
D O I：
10.1021/acsomega.8b02759
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The optimization of an organoaluminum catalytic system for the copolymerization of epoxides and anhydrides is presented. For this purpose, the influence of different variables in the process, such as catalysts, cocatalyst, solvent, or substrates, has been analyzed. Kinetic studies, a proposal for the catalytic mechanism, and full characterization of the copolymers obtained are also discussed. Finally, a new copolymer, poly(limonene succinate), obtained by the optimized catalytic system is reported.
引用
收藏
页码：17581 / 17589
页数：9
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