Catalytic Hydrodeoxygenation of Model Bio-oils Using HZSM-5 and Ni2P/HZM-5 Catalysts: Comprehension of Interaction

被引：8
作者：
Wang, Jundong [1 ]
Abdelouahed, Lokmane [1 ]
Xu, Jie [1 ]
Brodu, Nicolas [1 ]
Taouk, Bechara [1 ]
机构：
[1] Normandie Univ, INSA Rouen Normandie, UNIROUEN, LSPC Lab Securite Proc Chim,EA 4704, 685 Ave Univ, F-76801 St Etienne Du Rouvray, France
来源：
CHEMICAL ENGINEERING & TECHNOLOGY | 2021年 / 44卷 / 11期
关键词：
Alkyl substitution; Esterification; Hydrodeoxygenation; Model bio-oil; Ni2P; HZSM-5; catalyst; STEP HYDROGENATION-ESTERIFICATION; PYROLYSIS OIL; AQUEOUS-PHASE; ACETIC-ACID; PHENOLIC-COMPOUNDS; P-CRESOL; NICKEL; GUAIACOL; HYDROCARBONS; HYDROTREATMENT;
D O I：
10.1002/ceat.202100239
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Hydrodeoxygenation (HDO) of Mixture 1 (acetic acid and phenol) and Mixture 2 (acetone, acetic acid, phenol, 4-ethylguaiacolis, furfural, and water) as model bio-oils was performed to investigate the interactions. Ni2P/HZSM-5 catalysts exhibited higher activity than blank HZSM-5. The conversion rate of acetic acid enhanced with the increase of temperature, contrary to the value of phenol due to the differential adsorption capacity on active phases. Acetone can be formed by self-ketonization of acetic acid. Low temperatures favored esterification, while high temperatures promoted the synthesis of alkyl-substituted phenols and aromatic hydrocarbons via mainly alkyl substitution of phenol and benzene, respectively. Two reaction networks of model bio-oil HDO with the main reactions were proposed.
引用
收藏
页码：2126 / 2138
页数：13
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