Geometric conductive filament confinement by nanotips for resistive switching of HfO2-RRAM devices with high performance

被引:79
作者
Niu, Gang [1 ,2 ,3 ]
Calka, Pauline [1 ]
der Maur, Matthias Auf [4 ]
Santoni, Francesco [4 ]
Guha, Subhajit [1 ]
Fraschke, Mirko [1 ]
Hamoumou, Philippe [5 ]
Gautier, Brice [5 ]
Perez, Eduardo [1 ]
Walczyk, Christian [1 ]
Wenger, Christian [1 ]
Di Carlo, Aldo [4 ]
Alff, Lambert [6 ]
Schroeder, Thomas [1 ,7 ]
机构
[1] IHP GmbH Leibniz Inst Innovat Microelect, Technol Pk 25, D-15236 Frankfurt, Oder, Germany
[2] Xi An Jiao Tong Univ, Elect Mat Res Lab, Key Lab Minist Educ, Xian 710049, Peoples R China
[3] Xi An Jiao Tong Univ, Int Ctr Dielect Res, Xian 710049, Peoples R China
[4] Univ Roma Tor Vergata, Dept Elect Engn, Via Politecn 1, I-00133 Rome, Italy
[5] INSA Lyon, UMR CNRS 5270, INL, 7 Ave Jean Capelle, F-69621 Villeurbanne, France
[6] Tech Univ Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany
[7] Brandenburg Tech Univ Cottbus, Konrad Zuse Str 1, D-03046 Cottbus, Germany
关键词
TIO2; THIN-FILMS; IMPROVED UNIFORMITY;
D O I
10.1038/srep25757
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Filament-type HfO2-based RRAM has been considered as one of the most promising candidates for future non-volatile memories. Further improvement of the stability, particularly at the "OFF" state, of such devices is mainly hindered by resistance variation induced by the uncontrolled oxygen vacancies distribution and filament growth in HfO2 films. We report highly stable endurance of TiN/Ti/HfO2/Si-tip RRAM devices using a CMOS compatible nanotip method. Simulations indicate that the nanotip bottom electrode provides a local confinement for the electrical field and ionic current density; thus a nano-confinement for the oxygen vacancy distribution and nano-filament location is created by this approach. Conductive atomic force microscopy measurements confirm that the filaments form only on the nanotip region. Resistance switching by using pulses shows highly stable endurance for both ON and OFF modes, thanks to the geometric confinement of the conductive path and filament only above the nanotip. This nano-engineering approach opens a new pathway to realize forming-free RRAM devices with improved stability and reliability.
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页数:9
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