Asphaltene adsorption on kaolinite characterized by infrared and X-ray absorption spectroscopies

被引:35
作者
Bantignies, JL [1 ]
Moulin, CCD [1 ]
Dexpert, H [1 ]
机构
[1] Univ Paris 11, Lab Utilisat Rayonnement Electromagnet, F-91405 Orsay, France
关键词
X-ray absorption spectroscopy; infrared spectroscopy; kaolinite; asphaltenes; wettability;
D O I
10.1016/S0920-4105(98)00025-4
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The petroleum industry has observed that the trapping of oils in sedimentary rock is largely correlated to the presence of kaolinite clays in the rock's intergranular space. Using X-ray absorption and Fourier transform infrared (FTIR) spectroscopies, we studied at the microscopic level the adsorption process of asphaltenes in the presence and absence of water. We shaw that oil modifies the local environment of aluminum in this material and, more precisely, the AI-OH linkage. Finally, we show evidence that the process involved is different when the adsorption is performed with or without water. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:233 / 237
页数:5
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