Co-Based Nanosheets with Transitional Metal Doping for Oxygen Evolution Reaction

被引：2
作者：
Xiong, Chunhua [1 ]
Cai, Chao [2 ]
机构：
[1] Civil Aviat Flight Univ China, Coll Air Traff Management, Guanghan 618307, Peoples R China
[2] Univ Elect Sci & Technol China, Sch Phys, Chengdu 610054, Peoples R China
来源：
NANOMATERIALS | 2022年 / 12卷 / 11期
基金：
中国国家自然科学基金;
关键词：
transition metal-based materials; two-dimension nanosheets; amorphous materials; electrocatalysts; low bonded oxygen; HYDROGEN-EVOLUTION; BIFUNCTIONAL CATALYSTS; ULTRATHIN NANOSHEETS; EFFICIENT; MOS2; ELECTROCATALYSTS; LAYER; NANOCRYSTALS; OXIDE; COSE2;
D O I：
10.3390/nano12111788
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Activated two-dimension (2D) materials are used in various applications as high-performance catalysts. Breaking the long-range order of the basal plane of 2D materials can highly promote catalytic activity by supplying more active sites. Here we developed a method to synthesize ultrathin MCoOx (M = V, Mn, Fe, Ni, Cu, Zn) amorphous nanosheets (ANSs). These Co-based ANSs show high oxygen evolution reaction (OER) activity in alkaline solution due to the broken long-range order and the presence of abundant low bonded O on the basal plane. The stable Fe1Co1Ox ANSs also show an overpotential of ca. 240 mV of achieving 10 mA/cm(2) in OER, better than most reported transition metal-based electrocatalysts.
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页数：10
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