Aggregation-induced emission of a star-shape luminogen based on cyclohexanehexone substituted with AIE active tetraphenylethene functionality

被引：28

作者：

Rananaware, Anushri ^{[1
]}

La, Duong Duc ^{[1
]}

Bhosale, Sheshanath V. ^{[1
]}

机构：

[1] RMIT Univ, Sch Appl Sci, Melbourne, Vic 3001, Australia

来源：

RSC ADVANCES | 2015年 / 5卷 / 69期

基金：

澳大利亚研究理事会;

关键词：

INTRAMOLECULAR CHARGE-TRANSFER; MOLECULAR MATERIALS; EMITTERS; NANOPARTICLES; LUMINESCENCE; FLUORESCENCE; CELLS;

D O I：

10.1039/c5ra10413k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe a rigid star-shaped luminogen (HTCA) of cyclohexanehexone bearing six tetraphenylethene moieties, which exhibited strong aggregation-induced emission (AIE) characteristics. The twisting amplitude and steric hindrance of the TPE units were found to play a crucial role in their aggregated nano- to micro-structures. Interestingly, HTCA exhibits reversible piezofluorochromic behaviour through grinding which is reversed by treatment with solvents resulting in a cycle that can be repeated several times.

引用

页码：56270 / 56273

页数：4

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