Recent advances in the use of ionic liquids for electrochemical sensing

被引:240
作者
Silvester, Debbie S. [1 ]
机构
[1] Curtin Univ, Nanochem Res Inst, Dept Chem, Perth, WA 6845, Australia
关键词
VOLTAMMETRIC DETERMINATION; PLATINUM-ELECTRODES; GREEN SOLVENTS; SENSORS; GAS; INTERFACE; COMPOSITE; BIOCATALYSIS; ADSORPTION; REACTIVITY;
D O I
10.1039/c1an15699c
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Ionic Liquids are salts that are liquid at (or just above) room temperature. They possess several advantageous properties (e. g. high intrinsic conductivity, wide electrochemical windows, low volatility, high thermal stability and good solvating ability), which make them ideal as non-volatile electrolytes in electrochemical sensors. This mini-review article describes the recent uses of ionic liquids in electrochemical sensing applications (covering the last 3 years) in the context of voltammetric sensing at solid/liquid, liquid/liquid interfaces and carbon paste electrodes, as well as their use in gas sensing, ion-selective electrodes, and for detecting biological molecules, explosives and chemical warfare agents. A comment on the future direction and challenges in this field is also presented.
引用
收藏
页码:4871 / 4882
页数:12
相关论文
共 75 条
[1]   A Hybrid Nanosensor for TNT Vapor Detection [J].
Aguilar, Alvaro Diaz ;
Forzani, Erica S. ;
Leright, Mathew ;
Tsow, Francis ;
Cagan, Avi ;
Iglesias, Rodrigo A. ;
Nagahara, Larry A. ;
Amlani, Islamshah ;
Tsui, Raymond ;
Tao, N. J. .
NANO LETTERS, 2010, 10 (02) :380-384
[2]  
[Anonymous], ROSS KHIM ZH
[3]   DIRECT ELECTROCHEMISTRY OF REDOX PROTEINS [J].
ARMSTRONG, FA ;
HILL, HAO ;
WALTON, NJ .
ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (11) :407-413
[4]   An analytical view of ionic liquids [J].
Baker, GA ;
Baker, SN ;
Pandey, S ;
Bright, FV .
ANALYST, 2005, 130 (06) :800-808
[5]   Immiscible electrolyte systems based on asymmetric hydrophobic room temperature ionic liquids [J].
Ballantyne, Andrew D. ;
Brisdon, Alan K. ;
Dryfe, Robert A. W. .
CHEMICAL COMMUNICATIONS, 2008, (40) :4980-4982
[6]   The electrochemical oxidation of catechol and dopamine on platinum in 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C2mim][NTf2]) and 1-Butyl-3-methylimidazolium tetrafluoroborate ([C4mim][BF4]): Adsorption effects in ionic liquid voltammetry [J].
Barnes, Edward O. ;
O'Mahony, Aoife M. ;
Aldous, Leigh ;
Hardacre, Christopher ;
Compton, Richard G. .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2010, 646 (1-2) :11-17
[7]   Voltammetry in Room Temperature Ionic Liquids: Comparisons and Contrasts with Conventional Electrochemical Solvents. [J].
Barrosse-Antle, L. E. ;
Bond, A. M. ;
Compton, R. G. ;
O'Mahony, A. M. ;
Rogers, E. I. ;
Silvester, D. S. .
CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (02) :202-230
[8]   Reduction of carbon dioxide in 1-butyl-3-methylimidazolium acetate [J].
Barrosse-Antle, Laura E. ;
Compton, Richard G. .
CHEMICAL COMMUNICATIONS, 2009, (25) :3744-3746
[9]   The electrochemical reduction of the purines guanine and adenine at platinum electrodes in several room temperature ionic liquids [J].
Boldrin Zanoni, Maria Valnice ;
Rogers, Emma I. ;
Hardacre, Christopher ;
Compton, Richard G. .
ANALYTICA CHIMICA ACTA, 2010, 659 (1-2) :115-121
[10]   Non-haloaluminate room-temperature ionic liquids in electrochemistry - A review [J].
Buzzeo, MC ;
Evans, RG ;
Compton, RG .
CHEMPHYSCHEM, 2004, 5 (08) :1106-1120