Effect of the pendent groups on biobased polymers, obtained from click chemistry suitable, for the adsorption of organic pollutants from water

被引：2

作者：

Brirmi, Nour El Houda ^{[1
,2
]}

Chabbah, Taha ^{[1
,2
]}

Chatti, Saber ^{[1
]}

Schiets, Frederic ^{[3
]}

Casabianca, Herve ^{[3
]}

Marestin, Catherine ^{[4
]}

Mercier, Regis ^{[4
]}

Weidner, Steffen M. ^{[5
]}

Errachid, Abdelhamid ^{[3
]}

Jaffrezic-Renault, Nicole ^{[3
]}

Ben Romdhane, Hatem ^{[2
]}

机构：

[1] Natl Inst Res & Physicochem Anal INRAP, Biotechnopole SidiThabet, Ariana, Tunisia

[2] Univ Tunis El Manar, Fac Sci, Farhat Hached Univ Campus, Tunis, Tunisia

[3] Univ Lyon, Inst Analyt Sci, UMR 5280, 5 Rue Doua, F-69100 Villeurbanne, France

[4] Univ Lyon, Inst Polymer Mat IMP INSA, UMR 5223, Villeurbanne, France

[5] Fed Inst Mat Res & Testing, BAM, Berlin, Germany

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2022年 / 33卷 / 10期

关键词：

adsorption; biobased polymers; cycloaddition; pentafluoropyridine; phenolic compounds; NUCLEOPHILIC-SUBSTITUTION; BEARING 1,2,4-TRIAZOLE; EMERGING CONTAMINANTS; RENEWABLE RESOURCES; AQUEOUS-SOLUTION; DYE WASTEWATERS; ISOSORBIDE; POLYESTERS; REMOVAL; MICROPOLLUTANTS;

D O I：

10.1002/pat.5809

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this work, four triazole-based poly(ether-pyridine)s polymers were synthesized and used as an adsorbent for the removal of phenolic compounds from aqueous solutions. For this purpose, new fluoromonomers containing 1,2,3-triazole units were prepared by the Cu(I)-catalyzed 1,3-dipolar cycloaddition reaction and then used for the elaboration of novel poly(ether-pyridine-triazole)s (PEPTs) by direct polycondensation with isosorbide and bisphenol A. Chemical structure of fluorinated pyridinic monomers as well as resulting polymers was confirmed by H-1 and F-19 NMR spectroscopic methods. The thermal behavior of the obtained PEPTs was characterized using differential scanning calorimetry and thermogravimetric analysis. Results of sorption showed that polymers can be effectively used as a sorbent for the removal of polar organic pollutants. The isosorbide-based poly(ether-pyridine-triazole) which contains hydrophilic hydroxyl groups as pendants chains (P4) exhibited the highest sorption efficiencies (78%-100% after 1 h). In order to explain the results an adsorption mechanism mainly based on pi-pi interactions and hydrogen bonding with the pendent groups is proposed.

引用

页码：3551 / 3571

页数：21

共 73 条

[1] Rapid removal of organic micropollutants from water by a porous β-cyclodextrin polymer [J].

Alsbaiee, Alaaeddin ;

Smith, Brian J. ;

Xiao, Leilei ;

Ling, Yuhan ;

Helbling, Damian E. ;

Dichtel, William R. .

NATURE, 2016, 529 (7585) :190-U146

[2] Biological treatment of dye wastewaters using an anaerobic-oxic system [J].

An, H ;

Qian, Y ;

Gu, XS ;

Tang, WZ .

CHEMOSPHERE, 1996, 33 (12) :2533-2542

[3]

Anku W.W., 2017, PHENOLIC COMPOUNDS N, DOI DOI 10.5772/66927

[4]

[Anonymous], 1981, Adv. Heterocycl. Chem, DOI DOI 10.1016/S0065-2725(08)60040-9

[5] Low-cost adsorbents for heavy metals uptake from contaminated water: a review [J].

Babel, S ;

Kurniawan, TA .

JOURNAL OF HAZARDOUS MATERIALS, 2003, 97 (1-3) :219-243

[6] A review of potentially low-cost sorbents for heavy metals [J].

Bailey, SE ;

Olin, TJ ;

Bricka, RM ;

Adrian, DD .

WATER RESEARCH, 1999, 33 (11) :2469-2479

[7] Synthesis of 1,4-Disubstituted 1,2,3-Triazoles via 1,3-Dipolar Cycloaddition/C-N Coupling of Propargyl Alcohols/amines and Aryl Azides [J].

Bakherad, Mohammad ;

Ghalenoei, Ahmad Kakavand ;

Keivanloo, Ali .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 2018, 55 (12) :2683-2692

[8] HETEROCYCLIC POLYFLUORO-COMPOUNDS .4. NUCLEOPHILIC SUBSTITUTION IN PENTAFLUOROPYRIDINE - PREPARATION AND PROPERTIES OF SOME 4-SUBSTITUTED 2,3,5,6-TETRAFLUOROPYRIDINES [J].

BANKS, RE ;

BURGESS, JE ;

CHENG, WM ;

HASZELDINE, RN .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JAN) :575-+

[9] Synthesis and characterization of new fluorescent polyimides bearing 1,2,4-triazole and 1,2-diaryl quinoxaline: Study properties and application to the extraction/elimination of metallic ions from aqueous media [J].

Bazzar, Maasoomeh ;

Ghaemy, Mousa ;

Alizadeh, Raouf .

REACTIVE & FUNCTIONAL POLYMERS, 2013, 73 (03) :492-498

[10] Novel fluorescent light-emitting polymer composites bearing 1,2,4-triazole and quinoxaline moieties: Reinforcement and thermal stabilization with silicon carbide nanoparticles by epoxide functionalization [J].

Bazzar, Maasoomeh ;

Ghaemy, Mousa ;

Alizadeh, Raouf .

POLYMER DEGRADATION AND STABILITY, 2012, 97 (09) :1690-1703

← 1 2 3 4 5 6 7 8 →