Preparation and characterization of poly(3-methylthiophene)/CeY zeolite composites

被引:7
作者
Han, Pengyue
Liao, Junjie
Chang, Jinyu
Chang, Liping
Bao, Weiren [1 ]
机构
[1] Taiyuan Univ Technol, State Key Lab Breeding Base Coal Sci & Technol Co, Taiyuan 030024, Peoples R China
来源
RSC ADVANCES | 2015年 / 5卷 / 61期
基金
中国国家自然科学基金;
关键词
GLASSY-CARBON ELECTRODE; ELECTRICAL-CONDUCTIVITY; ADSORPTIVE REMOVAL; ASCORBIC-ACID; FILMS; NANOCOMPOSITES; POLYTHIOPHENE; NANOTUBES; THIOPHENE; DOPAMINE;
D O I
10.1039/c5ra08683c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly(3-methylthiophene)/CeY zeolite nanocomposites (P3MT/CeY) were prepared by chemical oxidative polymerization using anhydrous FeCl3 as the oxidizing agent. The physical and chemical properties of the prepared samples were measured using various characterization techniques, such as conductivity measurements, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA) and carbon-sulfur analysis. The prepared P3MT/CeY composites retained the crystalline structure of Y zeolite, which also enhanced thermostability. A 2000-fold increase in conductivity relative to a blank prepared using P3MT was observed for the composite prepared using a 3 : 1 g mL(-1) ratio of CeY and P3MT.
引用
收藏
页码:49343 / 49349
页数:7
相关论文
共 35 条
  • [11] HIGHLY CONDUCTING, SOLUBLE, AND ENVIRONMENTALLY-STABLE POLY(3-ALKYLTHIOPHENES)
    JEN, KY
    MILLER, GG
    ELSENBAUMER, RL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (17) : 1346 - 1347
  • [12] Poly(3-methylthiophene)/Vertically Aligned Multi-walled Carbon Nanotubes: Electrochemical Synthesis, Characterizations and Electrochemical Storage Properties in Ionic Liquids
    Lagoutte, Sebastien
    Aubert, Pierre-Henri
    Pinault, Mathieu
    Francois Tran-Van
    Mayne-L'Hermite, Martine
    Chevrot, Claude
    [J]. ELECTROCHIMICA ACTA, 2014, 130 : 754 - 765
  • [13] The Adsorptive Removal of Thiophene from Benzene over ZSM-5 Zeolite
    Liao, J.
    Bao, W.
    Chen, Y.
    Zhang, Y.
    Chang, L.
    [J]. ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2012, 34 (5-8) : 618 - 625
  • [14] Liao J.J., 2009, MOD CHEM IND, V29, P219
  • [15] Preparation of AlCl3/silica gel catalyst for simultaneously removing thiophene and olefins from coking benzene by inclosed grafting method
    Liao, Junjie
    Bao, Lei
    Wang, Wenbo
    Xie, Yuanyuan
    Chang, Jinyu
    Bao, Weiren
    Chang, Liping
    [J]. FUEL PROCESSING TECHNOLOGY, 2014, 117 : 38 - 43
  • [16] Preparation of γ-Al2O3 sorbents loaded with metal components and removal of thiophene from coking benzene
    Liao, Junjie
    Zhang, Yanjun
    Wang, Wenbo
    Xie, Yuanyuan
    Chang, Liping
    [J]. ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2012, 18 (3-4): : 181 - 187
  • [17] Adsorptive Removal of Thiophene from Benzene by NaY Zeolite Ion-Exchanged with Ce(IV)
    Liao, Junjie
    Wang, Wenbo
    Xie, Yuanyuan
    Zhang, Yanjun
    Chang, Liping
    Bao, Weiren
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 2012, 47 (13) : 1880 - 1885
  • [18] Adsorption and solvent desorption behavior of ion-exchanged modified Y zeolites for sulfur removal and for fuel cell applications
    Lin, Ligang
    Zhang, Yuzhong
    Zhang, Hongyu
    Lu, Fuwei
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 360 (02) : 753 - 759
  • [19] Novel poly(3-methylthiophene)-TiO2 hybrid materials for photovoltaic cells
    Lin, Yi-Jin
    Wang, Leeyih
    Chiu, Wen-Yen
    [J]. THIN SOLID FILMS, 2006, 511 (199-202) : 199 - 202
  • [20] One-Pot Synthesis of Conducting Poly(3-methylthiophene)-Grafted-Graphene Nanosheets
    Lingapppan, Niranjanmurthi
    Jeong, Jung Hyun
    Park, Jong Myung
    Lim, Kwon Taek
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2014, 14 (08) : 5708 - 5712