Copper-Catalyzed Hydrosulfonylation of Alkynes Employing Sulfonohydrazides toward the Synthesis of Vinyl Sulfones

被引：14

作者：

Hu, Deqing ^{[1
]}

Bai, Feicheng ^{[1
]}

Liu, Yunyun ^{[1
]}

Wan, Jie-Ping ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2016年 / 34卷 / 10期

基金：

中国国家自然科学基金;

关键词：

alkyne; sulfonohydrazide; hydrosulfonylation; copper catalysis; E-selectivity; CYSTEINE PROTEASE INHIBITORS; IODINE-MEDIATED SYNTHESIS; EFFICIENT ONE-POT; (E)-VINYL SULFONES; CINNAMIC-ACIDS; DECARBOXYLATIVE SULFONYLATION; METAL-FREE; SULFOXIDES; ALKENYLATION; OXIDATION;

D O I：

10.1002/cjoc.201600337

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrosulfonylation of terminal alkynes employing sulfonohydrazides has been accomplished with copper- catalysis in the presence of BPO (benzoic peroxyanhydride). Generally, excellent yield of the vinyl sulfone products has been acquired by heating the reaction at 70 degrees C in DMSO.

引用

页码：1053 / 1057

页数：5

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