Structural Changes of Fibroin During Chemical Processing of Silk Wastes

被引:2
|
作者
Susanin, A. I. [1 ]
Sashina, E. S. [1 ]
Zakharov, V. V. [2 ,3 ,4 ]
Zaborski, M. [5 ]
机构
[1] St Petersburg State Univ Ind Technol & Design, St Petersburg, Russia
[2] BP Konstantinov St Petersburg Nucl Phys Inst, NRC Kurchatov Inst, St Petersburg, Russia
[3] Russian Acad Sci, Inst Macromol Cpds, St Petersburg, Russia
[4] Peter Great St Petersburg Polytech Univ, St Petersburg, Russia
[5] Lodz Univ Technol, Lodz, Poland
关键词
BOMBYX-MORI; MOLECULAR-WEIGHT; FILMS; REGENERATION; BIOMATERIALS; CONFORMATION; DISSOLUTION; SCAFFOLDS;
D O I
10.1007/s10692-020-10123-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Structural changes occurring in fibroin during chemical processing of silk manufacturing wastes were studied using viscometry, electrophoresis in polyacrylamide gel with sodium dodecyl sulfate, IR spectroscopy, dynamic light scattering, and x-ray diffraction. Hydrolytic destruction increased and the fibroin molecular mass decreased if the pH of degumming solutions, temperature, and degumming time were increased. The optimal conditions for degumming silk fibers that minimized destruction of the polypeptide chains were proposed.
引用
收藏
页码:412 / 417
页数:6
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