Fabrication and high-performance microwave absorption of Ni@SnO2@PPy Core-Shell composite

A ternary composite of Ni@SnO2@PPy was synthesized via a three-step method, a facile hydrothermal route (Ni) in first step and (Ni@SnO2) in second step and followed by the in situ polymerization of PPy on the surface of Ni@SnO2. The obtained ternary composite was characterized by various instruments and the TEM analysis indicated that Ni particles were homogenously enwrapped by SnO2 and PPy. The Ni particles with a size of about 200-500 nm are core, SnO2 and PPy form shell. The electromagnetic properties of the core-shell structured Ni@SnO2@PPy (-30.1 dB) are much better than Ni (-10.75 dB) and Ni@SnO2 (-13.8 dB), which is mainly attributed to the improved impedance matching and enhanced interfacial effects. The maximum reflection loss of Ni@SnO2@PPy can reach -30.1 dB at 5.6 GHz and the absorption bandwidth with the reflection loss below -10 dB is 7.4 GHz (from 3.7 to 6.8 GHz, from 13.7 to 18 GHz) with the thickness of 3.5 mm. Our results indicate that the Ni@SnO2@PPy composite is a promising microwave absorbent with thin thickness, strong absorption, and broad bandwidth. (C) 2016 Elsevier B.V. All rights reserved.