Direct halogenative dearomatization of 2-naphthols by NXS (X = Cl, Br) in water

被引：29
|
作者：
Zhang, Zhenbei [1 ,2 ,3 ]
Sun, Qiangsheng [1 ,2 ]
Xu, Daqian [1 ,2 ]
Xia, Chungu [1 ,2 ]
Sun, Wei [1 ,2 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst LICP, Lanzhou 730000, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
来源：
GREEN CHEMISTRY | 2016年 / 18卷 / 20期
基金：
中国国家自然科学基金;
关键词：
HYDROXYLATIVE PHENOL DEAROMATIZATION; ONE-POT SYNTHESIS; ASYMMETRIC DEAROMATIZATION; INTRAMOLECULAR DEAROMATIZATION; ENANTIOSELECTIVE SYNTHESIS; OXIDATIVE DEAROMATIZATION; N-BROMOSUCCINIMIDE; BOND ACTIVATION; CHLORINATION; BROMINATION;
D O I：
10.1039/c6gc01673a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A direct halogenative dearomatization of substituted 2-naphthols was achieved by NXS (X = Cl, Br) in environmentally friendly water at room temperature. The reaction exhibited broad substrate scope, convenient operation and high yields (up to 99%), thus providing a facile route to dearomatic products and complex polycyclic frameworks.
引用
收藏
页码：5485 / 5492
页数：8
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