Hydrosols of Pd and Pd-H2: Influence of particle nature on the rate of catalytic reduction of hexacyanoferrate(III) ions with hydrogen

被引：5
作者：
Ershov, Boris G. [1 ]
Solovov, Roman D. [1 ]
机构：
[1] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Leninsky Pr 31-4, Moscow 119071, Russia
来源：
CATALYSIS COMMUNICATIONS | 2018年 / 103卷
基金：
俄罗斯基础研究基金会;
关键词：
Catalytic reduction; Nanoparticles of palladium; Hydrogen; Potassium hexacyanoferrate (III); PALLADIUM NANOPARTICLES; COLLOIDAL PALLADIUM; AQUEOUS-SOLUTIONS; SIZE; OXIDATION; DIOXIDE;
D O I：
10.1016/j.catcom.2017.09.017
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Palladium nanoparticles (5.3 +/- 1.4 nm) catalyze the reduction of hexacyanoferrate(III) ions with hydrogen in aqueous solution. The reaction rate substantially (approximately 6-fold) increases if the nanoparticles are pre-saturated with hydrogen. The difference between the electronic properties of hydrogenated and non-hydrogenated palladium particles determines their activity in dissociation of the hydrogen molecule into atoms.
引用
收藏
页码：34 / 37
页数：4
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