Kinetics and Mechanism of the Catalytic Reaction of Ozone with Toluene in the Liquid Phase

被引：3

作者：

Galstyan, S. G. ^{[1
]}

Tyupalo, N. F. ^{[1
]}

Galstyan, A. G. ^{[1
]}

机构：

[1] E Ukrainian Natl Univ, Inst Chem Technol, Rubezhnoye, Lugansk Oblast, Ukraine

来源：

PETROLEUM CHEMISTRY | 2011年 / 51卷 / 03期

关键词：

Ozone; Benzaldehyde; Benzyl Alcohol; Petroleum Chemistry; Redox Catalysis;

D O I：

10.1134/S0965544111030042

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The kinetics and product composition of the liquid-phase catalytic oxidation of toluene with an ozone air mixture were studied. It was shown that at low temperatures in an acetic anhydride medium in the presence of manganese acetate and an inorganic acid, oxidation develops mainly at the methyl group, yielding benzyl acetate, benzaldehyde, and benzylidene diacetate. The scheme of redox catalysis to explain the experimental data is discussed.

引用

页码：212 / 215

页数：4