Metal-organic nanoporous structures with anisotropic photoluminescence and magnetic properties and their use as sensors

被引：388

作者：

Harbuzaru, Bogdan V. ^{[1
]}

Corma, Avelino ^{[1
]}

Rey, Fernando ^{[1
]}

Atienzar, Pedro ^{[1
]}

Jorda, Jose L. ^{[1
]}

Garcia, Hermenegildo ^{[1
]}

Ananias, Duarte ^{[2
]}

Carlos, Luis D. ^{[2
]}

Rocha, Joao ^{[2
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim, E-46022 Valencia, Spain

[2] Univ Aveiro, Dept Chem & Phys, CICECO, P-3810193 Aveiro, Portugal

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 06期

关键词：

lanthanides; luminescence; metal-organic frameworks; microporous materials; sensors;

D O I：

10.1002/anie.200704702

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Shining bright: Porous metal-organic framework materials are important owing to their potential applications as sensors. A new family of nanoporous, multifunctional rare-earth metal-organic materials displays emission quantum yields and efficiencies that are the highest reported for solid-state Eu3+ compounds with organic ligands and magnetic properties. The picture shows [Gd,Eu]- and [Tb]-containing materials under UV light and interacting with a magnet. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1080 / 1083

页数：4

共 38 条

[1] Lanthanides in non-oxide glasses [J].

Adam, JL .

CHEMICAL REVIEWS, 2002, 102 (06) :2461-2476

[2] LUMINESCENCE STUDY OF COMPLEXATION OF EUROPIUM AND DICARBOXYLIC-ACIDS [J].

BARTHELEMY, PP ;

CHOPPIN, GR .

INORGANIC CHEMISTRY, 1989, 28 (17) :3354-3357

[3]

Carlos LD, 2000, ADV MATER, V12, P594, DOI 10.1002/(SICI)1521-4095(200004)12:8<594::AID-ADMA594>3.3.CO

[4]

2-J

[5] Microporous metal - Organic frameworks formed in a stepwise manner from luminescent building blocks [J].

Chandler, Brett D. ;

Cramb, David T. ;

Shimizu, George K. H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (32) :10403-10412

[6] Luminescent open metal sites within a metal-organic framework for sensing small molecules [J].

Chen, Banglin ;

Yang, Yu ;

Zapata, Fatima ;

Lin, Guannan ;

Qian, Guodong ;

Lobkovsky, Emil B. .

ADVANCED MATERIALS, 2007, 19 (13) :1693-+

[7] High-throughput synthesis and catalytic properties of a molecular sieve with 18-and 10-member rings [J].

Corma, Avelino ;

Diaz-Cabanas, Maria J. ;

Luis Jorda, Jose ;

Martinez, Cristina ;

Moliner, Manuel .

NATURE, 2006, 443 (7113) :842-845

[8] Oxygen sensors based on luminescence quenching [J].

Demas, JN ;

DeGraff, BA ;

Coleman, PB .

ANALYTICAL CHEMISTRY, 1999, 71 (23) :793A-800A

[9] MIL-103, a 3-D lanthanide-based metal organic framework with large one-dimensional tunnels and a high surface area [J].

Devic, T ;

Serre, C ;

Audebrand, N ;

Marrot, J ;

Férey, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (37) :12788-12789

[10] A high-silica zeolite with a 14-tetrahedral-atom pore opening [J].

Freyhardt, CC ;

Tsapatsis, M ;

Lobo, RF ;

Balkus, KJ ;

Davis, ME .

NATURE, 1996, 381 (6580) :295-298

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