Elastic constants and orientational viscosities of a bent-core nematic liquid crystal

被引:91
|
作者
Majumdar, M. [1 ]
Salamon, P. [2 ]
Jakli, A. [3 ,4 ]
Gleeson, J. T. [1 ]
Sprunt, S. [1 ]
机构
[1] Kent State Univ, Dept Phys, Kent, OH 44242 USA
[2] Hungarian Acad Sci, Res Inst Solid State Phys & Opt, H-1525 Budapest, Hungary
[3] Kent State Univ, Chem Phys Interdisciplinary Program, Kent, OH 44242 USA
[4] Kent State Univ, Inst Liquid Crystal, Kent, OH 44242 USA
来源
PHYSICAL REVIEW E | 2011年 / 83卷 / 03期
基金
美国国家科学基金会;
关键词
PHASE; RHEOLOGY;
D O I
10.1103/PhysRevE.83.031701
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Using a combination of dynamic light scattering and Freedericksz transitions induced in applied magnetic and electric fields, we have determined the absolute magnitudes of the Frank elastic constants and effective orientational viscosities of the bent-core nematic liquid crystal, 4-chloro-1,3-phenylene bis 4-[4'-(9-decenyloxy)benzoyloxy] benzoate. At a fixed temperature 2 degrees C below the isotropic-nematic transition, we find K-11 = 3.1 x 10(-12) N, K-22 = 0.31 x 10(-12) N, K-33 = 0.88 x 10(-12) N, eta(splay) = 1.1 Pa s, eta(twist) = 0.37 Pa s, and eta(bend) = 1.2 Pa s. The unusual anisotropies of these parameters are discussed in terms of short-range, smectic-C-like correlations among molecules in the nematic phase.
引用
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页数:8
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