The potential of palladacycles: More than just precatalysts

被引：1239
作者：
Dupont, J
Consorti, CS
Spencer, J
机构：
[1] Univ Fed Rio Grande do Sul, Inst Chem, Lab Mol Catalysis, BR-91501970 Porto Alegre, RS, Brazil
[2] James Black Fdn, London SE24 9JE, England
来源：
CHEMICAL REVIEWS | 2005年 / 105卷 / 06期
关键词：
D O I：
10.1021/cr030681r
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review covers isolated and well-defined compounds that contain a Pd-C bond stabilized by the intramolecular coordination of one or two neutral donor atoms (N, P, As, O, Se, or Se). Topics discussed include the methods of preparation, chiral cyclopalladated compounds, palladacycles in medicinal and biological chemistry, functionalization of Pd-C bonds, palladacycles as catalyst precursors, total syntheses, caveats, photoluminescent palladacycles, liquid crystals, and supramolecules and dendrimers.
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收藏
页码：2527 / 2571
页数：45
相关论文
共 512 条
[1]   STRUCTURAL DEPENDENCIES OF PYRAMIDAL INVERSION AT SULFUR AND SELENIUM IN THIO-ETHER AND SELENO-ETHER COMPLEXES OF PALLADIUM(II) AND PLATINUM(II) - A NUCLEAR MAGNETIC-RESONANCE STUDY [J].
ABEL, EW ;
BHARGAVA, SK ;
KITE, K ;
ORRELL, KG ;
SIK, V ;
WILLIAMS, BL .
POLYHEDRON, 1982, 1 (03) :289-298
[2]   High-efficiency red electrophosphorescence devices [J].
Adachi, C ;
Baldo, MA ;
Forrest, SR ;
Lamansky, S ;
Thompson, ME ;
Kwong, RC .
APPLIED PHYSICS LETTERS, 2001, 78 (11) :1622-1624
[3]   Nearly 100% internal phosphorescence efficiency in an organic light-emitting device [J].
Adachi, C ;
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) :5048-5051
[4]   Endothermic energy transfer: A mechanism for generating very efficient high-energy phosphorescent emission in organic materials [J].
Adachi, C ;
Kwong, RC ;
Djurovich, P ;
Adamovich, V ;
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
APPLIED PHYSICS LETTERS, 2001, 79 (13) :2082-2084
[5]   High-efficiency organic electrophosphorescent devices with tris(2-phenylpyridine)iridium doped into electron-transporting materials [J].
Adachi, C ;
Baldo, MA ;
Forrest, SR ;
Thompson, ME .
APPLIED PHYSICS LETTERS, 2000, 77 (06) :904-906
[6]   Preparation of 6-chloro-5-fluoroindole via the use of palladium and copper-mediated heterocyclisations [J].
Adams, DR ;
Duncton, MAJ ;
Roffey, JRA ;
Spencer, J .
TETRAHEDRON LETTERS, 2002, 43 (42) :7581-7583
[7]   Synthesis and spectroscopic characterization of organometallic chromophores for photoluminescent materials: cyclopalladated complexes [J].
Aiello, I ;
Ghedini, M ;
La Deda, M .
JOURNAL OF LUMINESCENCE, 2002, 96 (2-4) :249-259
[8]  
Alami M, 2001, EUR J INORG CHEM, P2675
[9]   Insertion of alkenyl sulfides into a palladium-aryl bond .2. Stabilization of sigma-yl-kS chelates and decomposition reactions through C-S cleavage [J].
Albeniz, AC ;
Espinet, P ;
Lin, YS .
ORGANOMETALLICS, 1996, 15 (23) :5010-5017
[10]   The cyclopalladation reaction of 2-phenylaniline revisited [J].
Albert, J ;
Granell, J ;
Zafrilla, J ;
Font-Bardia, M ;
Solans, X .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (02) :422-429
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