Hydrothermal synthesis and characterization of {[Ni2(NA)4(μ-H2O)]•2H2O}n (HNA = nicotinic acid) and its heterogeneous catalytic effect

被引：16

作者：

Ay, Burak ^{[1
]}

Yag, Gozde ^{[1
]}

Yildiz, Emel ^{[1
]}

Rheingold, Arnold L. ^{[2
]}

机构：

[1] Cukurova Univ, Arts & Sci Fac, Dept Chem, TR-01330 Adana, Turkey

[2] Univ Calif San Diego, Dept Chem & Biochem, San Diego, CA 92093 USA

来源：

POLYHEDRON | 2015年 / 88卷

关键词：

Hydrothermal reaction; 2,3-Pyridinedicarboxylic acid; Heterogeneous catalysis; Thymoquinone; Ni(II) coordination polymer; BIMETALLIC ORGANOARSONATE COMPOUNDS; NIGELLA-SATIVA OIL; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; OXIDATIVE STRESS; THYMOQUINONE; COMPLEXES; FRAMEWORKS; CU(II);

D O I：

10.1016/j.poly.2014.12.043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A carboxylate-bridged metal-organic coordination polymer ([Ni-2(NA)(4)(mu-H2O)center dot 2H(2)O}(n). (1, HNA = nicotinic acid) has been synthesized under hydrothermal conditions and characterized by FT-IR, TG/DTA, micro analysis and single-crystal X-ray diffraction. 1 has an interesting 3D network structure and adjacent networks are further connected together via strong pi-pi packing interactions. The thermal behavior and catalytic performance of 1 were investigated and its selectivity was measured as 100% for the oxidation of thymol (T) to thymoquinone (TQ). @ 2015 Elsevier Ltd. All rights reserved.

引用

页码：164 / 169

页数：6

共 69 条

[1] Antinociceptive effects of Nigella sativa oil and its major component, thymoquinone, in mice [J].

Abdel-Fattah, AFM ;

Matsumoto, K ;

Watanabe, H .

EUROPEAN JOURNAL OF PHARMACOLOGY, 2000, 400 (01) :89-97

[2] Neuropharmacological activity of Nigella sativa L. extracts [J].

Al-Naggar, TB ;

Gómez-Serranillos, MP ;

Carretero, ME ;

Villar, AM .

JOURNAL OF ETHNOPHARMACOLOGY, 2003, 88 (01) :63-68

[3] Hydrothermal synthesis, crystal structure and heterogeneous catalytic activity of a novel inorganic-organic hybrid complex, possessing infinite La-O-La linkages [J].

Ay, Burak ;

Yildiz, Emel ;

Protasiewicz, John D. ;

Rheingold, Arnold L. .

INORGANICA CHIMICA ACTA, 2013, 399 :208-213

[4] Hydrothermal synthesis of a novel μ-dihydroxo-bis(2,6-pyridinedicarboxylatoaquachromium(III)) complex and investigation of its catalytic activity [J].

Ay, Burak ;

Yildiz, Emel ;

Jones, Stephanie ;

Zubieta, Jon .

INORGANICA CHIMICA ACTA, 2012, 387 :15-19

[5] Metal-containing dicarboxylic acids as building blocks for lamellar inorganic-organic hybrid networks [J].

Beatty, AM ;

Helfrich, BA ;

Hogan, GA ;

Reed, BA .

CRYSTAL GROWTH & DESIGN, 2006, 6 (01) :122-126

[6] Synthesis, structures and antibacterial activities of two complexes of yttrium (III) with 2,6-pyridinedicarboxylate [J].

Cai, Mengjun ;

Chen, Jianding ;

Taha, Mohamed .

INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (01) :199-202

[7] Polycatenation, polythreading and polyknotting in coordination network chemistry [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289

[8] Synthesis, crystal structures and photoluminescence of Zn-Ln heterometallic polymers based on pyridine-2,3-dicarboxylic acid [J].

Chen, Li ;

Lin, Xiao-Ming ;

Ying, Yin ;

Zhan, Qing-Guang ;

Hong, Ze-Hong ;

Li, Jun-Yong ;

Weng, Ng Seik ;

Cai, Yue-Peng .

INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (08) :761-765

[9] Synthesis, structure, and photoelectronic effects of a uranium-zinc-organic coordination polymer containing infinite metal oxide sheets [J].

Chen, W ;

Yuan, HM ;

Wang, JY ;

Liu, ZY ;

Xu, JJ ;

Yang, M ;

Chen, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (31) :9266-9267

[10] Bipyridyl second ligand dependent structural and magnetic properties of Cu(II) complexes with pyridine-2,6-dicarboxylate and water molecule as first ligand [J].

Cui, Shuxin ;

Zhao, Yulong ;

Zhang, Jingping ;

Liu, Qun ;

Zhang, Yan .

CRYSTAL GROWTH & DESIGN, 2008, 8 (10) :3803-3809

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