Structure of a new binuclear complex of tungsten [W2S4Cl2(dppe)2]•2CH3CN

被引：0

作者：

Artemkina, S. B. ^{[1
,2
]}

Ledneva, A. Yu. ^{[1
]}

Piryazev, D. A. ^{[1
]}

Virovets, A. V. ^{[1
]}

Mironov, Yu. V. ^{[1
]}

Fedorov, V. E. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 01期

关键词：

tungsten; sulfur; binuclear complex; synthesis; crystal structure; Raman spectrum; CRYSTAL-STRUCTURE; MO; MOLYBDENUM(V); REACTIVITY; PRECURSORS;

D O I：

10.1134/S0022476615010175

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the reaction of (Et4N)(2)[W2S4Cl4] with 1,2-bis(diphenylphosphino)ethane in acetonitrile a new binuclear complex of tungsten(V) [W2S4Cl2(dppe)(2)]center dot 2CH(3)CN is obtained. Its crystal structure is solved in the triclinic space group P-1 with the following unit cell parameters a = 10.1202(16) , b = 11.758(2) , c = 12.648(2) , alpha = 104.324(5)A degrees, beta = 106.469(5)A degrees, gamma = 97.587(5)A degrees, V = 1364.9(4) (3), Z = 1, with the final refinement parameters R (1) = 0.0545, wR (2) = 0.1053. The work describes the synthesis, crystal structure, and Raman spectrum of the [W2S4Cl2(dppe)(2)]center dot 2CH(3)CN complex.

引用

页码：121 / 125

页数：5

共 28 条

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